# US 2026/0074209 A1 · Vanadium oxide composite and battery using same

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- Number: US 2026/0074209 A1
- Document ID: US20260074209A1
- Status: Published application
- Kind: A1
- Application number: 19/389,890
- Filed: 2025-11-14
- Published: 2026-03-12
- Earliest claimed: 2023-05-22
- Assignees: Panasonic Intellectual Property Management Co., Ltd.
- Applicants: Panasonic Intellectual Property Management Co., Ltd.
- Inventors: Ryuhei KATAYAMA; Yoshiaki TANAKA; Kaori SHINODA
- Web page: https://patentgrep.com/patent/US20260074209A1

## CPC

- H01M 4/485: of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence)
- C01G 31/00: Compounds of vanadium
- C01G 31/02: Oxides
- H01M 4/02: Electrodes composed of, or comprising, active material
- H01M 4/13: Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M 4/131: Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M 4/1391: of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M 4/362: {Composites}
- H01M 4/364: {as mixtures}
- H01M 4/366: {as layered products}
- H01M 4/48: of inorganic oxides or hydroxides
- H01M 4/483: {for non-aqueous cells (H01M4/485 takes precedence)}
- H01M 4/5825: {Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines}
- H01M 4/62: Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M 4/624: {Electric conductive fillers}
- H01M 4/625: {Carbon or graphite}
- H01M 4/626: {Metals}
- H01M 10/052: Li-accumulators
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- C01P 2002/50: Solid solutions
- C01P 2004/61: Micrometer sized, i.e. from 1-100 micrometer
- C01P 2004/80: Particles consisting of a mixture of two or more inorganic phases
- C01P 2004/84: one phase coated with the other
- C01P 2006/40: Electric properties
- H01M 2004/021: {Physical characteristics, e.g. porosity, surface area}
- H01M 2004/027: {Negative electrodes}
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- C01G: COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts or peroxyacids C01B15/00; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium, or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds containing nitrogen, other non-metals and metal C01B21/082}; metal amides C01B21/092; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanamide C01C3/16; thiocyanates C01C3/20)
- C01P: INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A vanadium oxide composite of the present disclosure includes: a particle including a vanadium oxide; and an electrically conductive material at least partially coating a surface of the particle. A surface coverage of the particle by the electrically conductive material is 30% or more. The vanadium oxide composite has an average particle size of 0.5 μm or more and 5.0 μm or less.

## Claims

### Claim 1

A vanadium oxide composite comprising:
a particle including a vanadium oxide; and
an electrically conductive material at least partially coating a surface of the particle, wherein
a surface coverage of the particle by the electrically conductive material is 30% or more, and
the vanadium oxide composite has an average particle size of 0.5 μm or more and 5.0 μm or less.

### Claim 2 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the electrically conductive material is a carbon material.

### Claim 3 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the average particle size is 0.55 μm or more and 4.5 μm or less.

### Claim 4 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the average particle size is 0.6 μm or more and 4.0 μm or less.

### Claim 5 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the average particle size is 0.8 μm or more and 3.0 μm or less.

### Claim 6 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the surface coverage is 40% or more.

### Claim 7 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the surface coverage is 55% or more.

### Claim 8 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the surface coverage is 70% or less.

### Claim 9 (depends on 1)

The vanadium oxide composite according to claim 1, wherein the vanadium oxide is represented by a composition formula (1) Li3+xV1−xMxO4, where 0≤x<1 is satisfied, and M is at least one element selected from the group consisting of a tetravalent metal element and a tetravalent metalloid element.

### Claim 10 (depends on 9)

The vanadium oxide composite according to claim 9, wherein 0<x<1 is satisfied in the composition formula (1).

### Claim 11 (depends on 9)

The vanadium oxide composite according to claim 9, wherein the M includes Ti in the composition formula (1).

### Claim 12 (depends on 1)

A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte layer disposed between the positive electrode and the negative electrode, wherein
the negative electrode includes the vanadium oxide composite according to claim 1.

### Claim 13 (depends on 12)

The battery according to claim 12, wherein the negative electrode further includes a conductive additive.

### Claim 14 (depends on 12)

The battery according to claim 12, wherein
the negative electrode further includes a conductive additive, and
the surface coverage of the vanadium oxide composite is 30% or more and 60% or less.

### Claim 15 (depends on 14)

The battery according to claim 14, wherein a content of the conductive additive is 2.0 wt % or more and 5.0 wt % or less.
