Polycyclic aromatic bridges for molecular electronic sensors
AssigneeSemiconBio Inc.
InventorsBarry MERRIMAN, Tim GEISER, Paul W. MOLA, Darryl RIDEOUT
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Abstract
In various embodiments, synthetic bridge molecules are disclosed, usable in molecular electronics sensors. In various aspects, bridge molecules comprise fused ring polycyclic aromatic hydrocarbon structures in the shape of a long and narrow ribbon, with end groups on opposite short ends for selective binding to metal electrodes, one or more substituents near the midpoint of a long edge for binding to a probe molecule, and one or more additional substituent groups for solubility or other effects. In various embodiments, the bridge molecules herein are conducting, and provide a closed circuit in a sensor when forming a bridge between gapped electrodes.
Claims4
A synthetic bridge molecule for use in a molecular electronics sensor, the molecule comprising:
- an electrically conductive sp2-hybridized polycyclic aromatic hydrocarbon nanoribbon of fused benzene rings each in a single fixed orientation, the nanoribbon having a generally rectangular sheet-like configuration and a periphery defined by two substantially parallel longer top and bottom edges and two substantially parallel shorter left and right edges, wherein the single fixed orientation of each fused ring results in a zig-zag periodicity along either the longer edges or the shorter edges of the nanoribbon, and wherein the nanoribbon measures from about 3 nm to about 100 nm in length and from about 0.23 nm to about 23 nm in width;
- a substituent L covalently bonded to the left shorter edge of the nanoribbon;
- a substituent R covalently bonded to the right shorter edge of the nanoribbon, wherein L and R each comprise at least one sulfur atom or a carbene precursor moiety capable of bonding to a metal electrode or a metal contact disposed on an electrode;
- at least one attachment group P covalently bonded to any edge of the nanoribbon and capable of bonding to a probe molecule;
- and
- at least one substituent S covalently bonded to any edge of the nanoribbon, the substituent capable of affecting at least one of solubility or conformation of the synthetic bridge molecule or capable of promoting self-assembly of the synthetic bridge molecule to at least one of the metal electrode, the metal contact on an electrode, or the probe molecule, in fabrication of the molecular electronics sensor.
4-13. (canceled)
Dependencies are inferred from the claim text.