Melamine process with purification of melamine offgas
AssigneeCasale SA
InventorSimone Gamba
Life of this patent
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Abstract
A process for the synthesis of melamine including the purification of the offgas released by the synthesis of melamine by means of a single purification stage (6); in the purification stage (6), the offgas (3) is washed with fresh urea melt and with a recirculated urea melt (8) containing ammonia and melamine precursors (5); said recirculated urea melt is withdrawn from bottom of the single purification stage (6) and cooled in a shell and tube heat exchanger (11), optionally after mixing with the fresh urea melt (15), to a temperature of at least 165° C. preferably in the range 165° C. to 245° C. prior to reintroduction in the purification stage.
Claims18
A process for the synthesis of melamine including the steps of:
- reacting a feed stream of urea melt in a melamine synthesis section under non-catalytic high pressure melamine synthesis conditions to generate a raw melamine product and an offgas comprising ammonia and carbon dioxide,
- subjecting said offgas to a purification process by washing the offgas with urea melt, to obtain a purified offgas and a urea melt which, as a result of the washing process, contains ammonia and melamine precursors,
- wherein the purification process is performed in a single purification stage, said offgas to be purified and said urea melt being introduced in said single purification stage and said purified offgas being extracted from said single purification stage,
- wherein the urea melt used for the offgas washing process in the purification stage includes a fresh urea melt and a recirculated urea melt,
- wherein said recirculated urea melt is withdrawn from said purification stage after contact with the offgas, subjected to a cooling process and reintroduced in said purification stage after said cooling process;
- wherein said cooling process is performed in a shell and tube heat exchanger and where, in the cooling process, said recirculated urea melt is cooled to a temperature of not less than 165° C.
Dependencies are inferred from the claim text.