# US 2026/0061384 A1 · Membrane-based autothermal ammonia reactor > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2026/0061384 A1 - Document ID: US20260061384A1 - Status: Published application - Kind: A1 - Application number: 18/824,384 - Filed: 2024-09-04 - Published: 2026-03-05 - Earliest claimed: 2024-09-04 - Assignees: Saudi Arabian Oil Company - Applicants: Saudi Arabian Oil Company - Inventors: Osamah Siddiqui; Bandar Solami - Web page: https://patentgrep.com/patent/US20260061384A1 ## CPC - B01J 8/065: {Feeding reactive fluids} - B01D 53/229: {Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)} - B01D 53/261: {by adsorption} - B01D 69/04: Tubular membranes - B01J 8/067: {Heating or cooling the reactor (B01J8/062 takes precedence)} - B01J 19/2475: {Membrane reactors} - C01B 3/047: Decomposition of ammonia - C01B 3/501: by diffusion - B01D 2256/16: Hydrogen - B01D 2257/102: Nitrogen - B01D 2257/80: Water - B01J 2208/065: Heating or cooling the reactor - C01B 2203/0277: containing a catalytic decomposition step - C01B 2203/041: In-situ membrane purification during hydrogen production - C01B 2203/0844: the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294 - Y02E 60/36: Hydrogen production from non-carbon containing sources, e.g. by water electrolysis - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28) - C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C} - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract An autothermal ammonia reactor includes a chamber, a hydrogen-separation membrane within the chamber, and an ammonia decomposition catalyst. The chamber receives ammonia and air. The chamber including a combustion zone, a catalytic zone, and a hydrogen zone. The catalytic zone is in thermal communication with the combustion zone. The chamber directs the air and a portion of the ammonia from the fluid inlet to the combustion zone to allow the air and ammonia to exothermically react to generate thermal energy. The chamber directs another portion of the ammonia into the catalytic zone to decompose into hydrogen and nitrogen as the ammonia is exposed to the thermal energy from the combustion zone and contacts the catalyst. The chamber directs the hydrogen from the catalytic zone, through a surface of the hydrogen-separation membrane, to the hydrogen zone to allow the hydrogen to exit the chamber through the fluid outlet. ## Claims ### Claim 1 An autothermal ammonia reactor, comprising: a chamber comprising a fluid inlet and a fluid outlet, the chamber arranged to receive, through the fluid inlet, ammonia and air, the chamber comprising a combustion zone fluidly coupled with the inlet; a hydrogen-separation membrane disposed within the chamber, the chamber comprising a catalytic zone and a hydrogen zone at the hydrogen-separation membrane and downstream of the catalytic zone, the hydrogen-separation membrane separating the catalytic zone from the hydrogen zone such that the catalytic zone is either surrounded by or surrounding the hydrogen zone and the hydrogen-separation membrane, the catalytic zone being in thermal communication with the combustion zone and the hydrogen zone being fluidly coupled with the fluid outlet; and an ammonia decomposition catalyst disposed within the catalytic zone; wherein the chamber is arranged to direct the air and a portion of the ammonia from the fluid inlet to the combustion zone to allow the air and the portion of the ammonia to exothermically react to generate thermal energy, the chamber arranged to direct another portion of the ammonia into the catalytic zone to decompose into hydrogen and nitrogen as the ammonia is exposed to the thermal energy from the combustion zone and contacts the ammonia decomposition catalyst, and the chamber is arranged to direct the hydrogen from the catalytic zone, through a surface of the hydrogen-separation membrane, to the hydrogen zone to allow the hydrogen to exit the chamber through the fluid outlet. ### Claim 2 (depends on 1) The autothermal ammonia reactor of claim 1, wherein the air and the portion of the ammonia exothermically react to produce nitrogen and water, and the chamber is arranged to direct the produced nitrogen and water out of the chamber. ### Claim 3 (depends on 2) The autothermal ammonia reactor of claim 2, further comprising a drying zone disposed between the combustion zone and the catalytic zone, the drying zone comprising a drying agent configured to absorb at least some of the water produced in the combustion zone. ### Claim 4 (depends on 3) The autothermal ammonia reactor of claim 3, wherein the drying agent is regenerated in-situ through a passage of a drying gas. ### Claim 5 (depends on 1) The autothermal ammonia reactor of claim 1, wherein the hydrogen-separation membrane comprises a retentate side facing the catalytic zone and a permeate side facing the hydrogen zone, the hydrogen-separation membrane arranged to prevent the nitrogen from flowing from the catalytic zone to the hydrogen zone such that nitrogen is kept in the catalytic zone in contact with the retentate side, the catalytic zone fluidly coupled to a second fluid outlet through which the nitrogen exits the chamber. ### Claim 6 An ammonia reactor, comprising: a chamber comprising a fluid inlet and a fluid outlet, the chamber arranged to receive, through the fluid inlet, ammonia and a reaction fluid, the chamber comprising a combustion zone fluidly coupled with the inlet, a decomposition zone in thermal communication with the combustion zone, and a hydrogen zone downstream of the decomposition zone, the hydrogen zone fluidly coupled with the fluid outlet; and a hydrogen-separation membrane disposed within the chamber and separating the decomposition zone from the hydrogen zone; wherein the chamber is arranged to direct the reaction fluid and ammonia from the fluid inlet to the combustion zone to allow the reaction fluid and ammonia to exothermically react to generate thermal energy, the chamber arranged to direct ammonia to the decomposition zone to decompose into hydrogen and nitrogen under the thermal energy from the combustion zone, and the chamber is arranged to direct the hydrogen from the decomposition zone, through a surface of the hydrogen-separation membrane, to the hydrogen zone to allow the hydrogen to exit the chamber through the fluid outlet. ### Claim 7 (depends on 6) The ammonia reactor of claim 6, wherein the hydrogen zone is at the hydrogen-separation membrane, the hydrogen-separation membrane comprising a cylindrical shape or a ring-like shape such that the decomposition zone is either surrounded by or surrounding the hydrogen-separation membrane, and the decomposition zone receives, from the combustion zone, unreacted ammonia. ### Claim 8 (depends on 7) The ammonia reactor of claim 7, wherein the hydrogen-separation membrane comprises a cylindrical shape at a core of the chamber, the hydrogen-separation membrane comprising an external and retentate surface that defines, with an internal wall of the chamber, an annulus, the decomposition zone residing within the annulus, and the hydrogen flows inwardly from the annulus to the hydrogen zone within the hydrogen-separation membrane. ### Claim 9 (depends on 8) The ammonia reactor of claim 8, wherein the hydrogen zone is at the core of the chamber and spans a length of the chamber, the combustion zone spans the length of the chamber, and the chamber comprises a concentric volume fluidly decoupled from and surrounding the combustion zone, the combustion zone residing at the concentric volume. ### Claim 10 (depends on 7) The ammonia reactor of claim 7, wherein the hydrogen-separation membrane comprises a ring-like shape, the hydrogen-separation membrane comprising an internal and retentate surface facing an inner volume at a core of the chamber, the decomposition zone residing within the inner volume at the core of the chamber, and the hydrogen flows outwardly from the inner volume to the hydrogen zone within the hydrogen-separation membrane. ### Claim 11 (depends on 10) The ammonia reactor of claim 10, wherein the hydrogen zone spans a length of the chamber such that the hydrogen zone surrounds the combustion zone. ### Claim 12 (depends on 6) The ammonia reactor of claim 6, wherein the chamber further comprises a second inlet fluidly coupled with the hydrogen zone and configured to receive a sweep gas to sweep the hydrogen out of the chamber. ### Claim 13 (depends on 6) The ammonia reactor of claim 6, wherein the chamber further comprises a second decomposition zone disposed between the combustion zone and the decomposition zone and comprising a high-temperature ammonia decomposition catalyst bed, the second decomposition zone exposed to a temperature from the combustion zone that is higher than a temperature to which the decomposition zone is exposed. ### Claim 14 (depends on 6) The ammonia reactor of claim 6, wherein the reaction fluid comprises oxygen that exothermically reacts with the ammonia to produce nitrogen and water, and the chamber further comprises a drying zone disposed between the combustion zone and the decomposition zone and comprising a drying agent configured to absorb at least some of the water produced in the combustion zone. ### Claim 15 (depends on 6) The ammonia reactor of claim 6, wherein the hydrogen-separation membrane comprises a retentate side facing the decomposition zone and a permeate side facing the hydrogen zone, the hydrogen-separation membrane arranged to prevent the nitrogen from flowing from the decomposition zone to the hydrogen zone such that nitrogen is kept in the decomposition zone in contact with the retentate side, the decomposition zone fluidly coupled to a second fluid outlet through which the nitrogen exits the chamber. ### Claim 16 (depends on 6) The ammonia reactor of claim 6, further comprising an ammonia decomposition catalyst disposed within the decomposition zone, the decomposition zone comprising a catalytic zone, the chamber arranged to direct unreacted ammonia to the catalytic zone to decompose into hydrogen and nitrogen under the thermal energy from the combustion zone and upon contact with the ammonia decomposition catalyst. ### Claim 17 (depends on 16) The ammonia reactor of claim 16, wherein the reaction fluid comprises oxygen that exothermically reacts with the ammonia to produce nitrogen and water, and the hydrogen-separation membrane is water-resistant. ### Claim 18 A method, comprising: directing ammonia and a reaction fluid into a combustion zone of a chamber of an ammonia reactor, allowing the ammonia and reaction fluid to exothermically react to generate thermal energy in the combustion zone; directing ammonia into a decomposition zone of the chamber, the decomposition zone in thermal communication with the combustion zone so that the ammonia in the decomposition zone decomposes, under the thermal energy from the combustion zone, into hydrogen and nitrogen; and directing the hydrogen from the decomposition zone, through a surface of a hydrogen-separation membrane disposed within the chamber, to a hydrogen zone to allow the hydrogen to exit the chamber. ### Claim 19 (depends on 18) The method of claim 18, wherein the reaction fluid comprises at least one of air or hydrogen, and directing the ammonia and the reaction fluid comprises directing dry ammonia from a distillation column into the chamber, and directing at least one of (i) air from an air source into the chamber, or (ii) hydrogen from a gas separator into the chamber. ### Claim 20 (depends on 18) The method of claim 18, further comprising directing the hydrogen out of the chamber into a gas separator that separates a sweep gas from the hydrogen.