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US 2026/0056469 A1Published application
Iodonium salt, chemically amplified positive resist composition and resist pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorMasahiro Fukushima
Life of this patent
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Abstract
A betaine type iodonium salt containing a C6-C18 alkyl or C4-C18 fluorinated alkyl group and having a iodonium cation and a carboxylate anion within a common molecule is a useful quencher. A chemically amplified positive resist composition comprising the iodonium salt exhibits improved lithography properties such as resolution, LER and pattern profile when processed by photolithography.
Claims19
A iodonium salt having the formula (A):
- wherein n1 is 0 or 1, n2 is 0, 1, 2, 3 or 4, n3 is 0 or 1, n4 is 0, 1, 2, 3 or 4,
- LA is a single bond, ether bond, ester bond, sulfonic ester bond, carbonate bond or carbamate bond,
- Ralk is a C6-C18 alkyl group or C4-C18 fluorinated alkyl group;
- when R1 is a C6-C18 alkyl group, the alkyl group has at least one straight chain structure of 6 or more carbon atoms;
- when Ralk is a C4-C18 fluorinated alkyl group, the fluorinated alkyl group has at least two groups selected from —CF2— and —CF3;
- the alkyl or fluorinated alkyl group may have some —CH2— replaced by an ether bond or carbonyl group and may contain a cyclic structure selected from cyclopentane, cyclohexane, adamantane, norbornyl and benzene rings at its end or in a carbon-carbon bond,
- R1 is halogen, nitro, cyano, hydroxy, a C1-C20 hydrocarbyl group which may contain a heteroatom, C1-C20 hydrocarbyloxy group which may contain a heteroatom, or C1-C20 hydrocarbylthio group which may contain a heteroatom;
- when n2 is 2, 3 or 4, a plurality of R1 may be identical or different and may bond together to form a ring with the carbon atoms to which they are attached,
- R2 is halogen, nitro, cyano, hydroxy, a C1-C20 hydrocarbyl group which may contain a heteroatom, C1-C20 hydrocarbyloxy group which may contain a heteroatom, or C1-C20 hydrocarbylthio group which may contain a heteroatom;
- when n4 is 2, 3 or 4, a plurality of R2 may be identical or different and may bond together to form a ring with the carbon atoms to which they are attached,
- two aromatic rings attached to I+ in the formula may bond together to form a ring with the iodine atom to which they are attached.
8 more elements
Dependencies are inferred from the claim text.