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US 2026/0044075 A1Published application
Onium salt, chemically amplified resist composition, and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorMasahiro Fukushima
Life of this patent
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Abstract
The onium salt comprises a cation having the following formula (1A) and an anion having the following formula (1B). The onium salt can be used for a chemically amplified resist composition having high sensitivity, excellent resolution, and improved lithographic performances such as EL, LWR, CDU, and DOF and capable of suppressing resist pattern collapse particularly in photolithography using high-energy radiation such as far ultraviolet rays, electron beam (EB), and EUV.
Claims19
An onium salt comprising a cation having the following formula (1A) and an anion having the following formula (1B):
- wherein p is 1, 2, or 3, n1 is 0 or 1, n2 is 1 or 2, n3 is 0, 1, 2, or 3, provided that, when n1 is 0, 1≤n2+n3≤5, and when n1 is 1, 1≤n2+n3≤7,
- R1 is a halogen atom, a nitro group, a hydroxy group, a carboxy group, a C1-C20 hydrocarbyl group which may contain a heteroatom, a C1-C20 hydrocarbyloxy group which may contain a heteroatom, a C1-C20 hydrocarbylthio group which may contain a heteroatom, or a C2-C20 hydrocarbyloxycarbonyl group which may contain a heteroatom, when n3 is 2 or 3, respective R1 may be the same as or different from each other, and two R1's may bond together to form a ring with the carbon atom to which they are attached,
- R2 is a halogen atom, or a C1-C30 hydrocarbyl group which may contain a heteroatom, when p is 1, two R2's may be the same as or different from each other, two of three substituents bonded to S+ may bond together to form a ring with the sulfur atom to which they are bonded, and
- wherein n11 is 0 or 1, n12 is 1, 2, 3, or 4, n13 is 0, 1, or 2, n14 is 0, 1, 2, 3, or 4, provided that, when n11 is 0, 2≤n12+n13+n14≤5, and when n1 is 1, 2≤n12+n13+n14≤7,
- LA is a single bond, an oxygen atom, a sulfur atom, an ester bond, or a carbonate bond,
- R3 is a hydrogen atom, or a C1-C20 hydrocarbyl group which may contain a heteroatom when LA is a single bond, and is a hydrogen atom, a C1-C20 hydrocarbyl group which may contain a heteroatom (provided that an acid labile group is excluded), or an acid labile group when LA is an oxygen atom, a sulfur atom, an ester bond, or a carbonate bond, and
- R4 is a halogen atom other than an iodine atom, a nitro group, a cyano group, a C1-C20 hydrocarbyl group which may contain a heteroatom, a C1-C20 hydrocarbyloxy group which may contain a heteroatom, or a C1-C20 hydrocarbylthio group which may contain a heteroatom.
4 more elements
Dependencies are inferred from the claim text.