Pressed, self-solidifying, solid cleaning compositions and methods of making them
AssigneeEcolab USA Inc.
InventorsROGER L. STOLTE, MICHAEL P. DZIUK, MELISSA C. MEINKE, MATTHEW C. PORTER
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Abstract
The present invention relates to a method of making a solid cleaning composition. The method can include pressing and/or vibrating a flowable solid of a self-solidifying cleaning composition. For a self-solidifying cleaning composition, pressing and/or vibrating a flowable solid determines the shape and density of the solid but is not required for forming a solid. The method can employ a concrete block machine for pressing and/or vibrating. The present invention also relates to a solid cleaning composition made by the method and to solid cleaning compositions including particles bound together by a binding agent.
Claims16
1-20. (canceled)
21:
- A stable solid composition comprising:
- a flowable self-solidifying cleaning composition pressed into a pressed solid and comprising less than 0.5 wt-% phosphorus-containing compounds comprising:
- up to about 15 wt-% water;
- about 20 wt-% to about 70 wt-% of an alkali metal carbonate;
- about 1 wt-% to about 40 wt-% of an alkali metal bicarbonate;
- about 1 wt-% to about 30 wt-% of a sequestrant;
- and
- about 1 wt-% to about 20 wt-% of a biodegradable aminocarboxylate selected from the group consisting of ethanoldiglycine, methylglycinediacetic acid, iminodisuccinic acid, N,N-bis (carboxylatomethyl)-L-glutamate, [S,S]-ethylenediaminedisuccinic acid (EDDS), 3-hydroxy-2,2′-iminodisuccinate (HIDS), and salt thereof.
22:
- The solid composition of claim 21, comprising from about 2 wt-% to about 15 wt-% water.
23:
- The solid composition of claim 21, comprising from about 5 wt-% to about 20 wt-% of the biodegradable aminocarboxylate.
24:
- The solid composition of claim 21, further comprising additional cleaning agents.
25:
- The solid composition of claim 24, wherein the cleaning agent is a surfactant in the amount from about 0.5 wt-% to about 10 wt-% surfactant.
26:
- The solid composition of claim 21, further comprising a binding agent that is comprised of stearic monoethanolamide, lauric diethanolamide, an alkylamide, a solid polyethylene glycol, a solid EO/PO block copolymer, water insoluble starches or combinations thereof.
27:
- The solid composition of claim 21, further comprising a hydrated carboxylate.
28:
- The solid composition of claim 27, wherein the hydrated carboxylate comprises a salt of a 1-12 carbon carboxylic acid comprising 1-3 carboxyl moieties.
29:
- The solid composition of claim 28, wherein the carboxylate comprises a salt of acetic acid, gluconic acid, malic acid, succinic acid, glutaric acid, adipic acid, tartaric acid, citric acid, or mixture thereof.
30:
- The solid composition of claim 28, wherein the hydrated carboxylate comprises a salt of acetic acid, tartaric acid, citric acid, or mixture thereof.
31:
- The solid composition of claim 21, wherein the composition comprises less than 0.5% nitrilotriacetic acid.
32:
- The solid composition of claim 21, wherein the composition comprises about 1 wt-% to about 10 wt-% of the biodegradable aminocarboxylate.
33:
- The solid composition of claim 21, wherein the solid composition is about 40 grams to about 11,000 grams.
34:
- The solid composition of claim 21, wherein the solid is in the form of a pellet, a tablet, a lozenge, a puck, a briquette, a brick, or a unit dose.
35:
- A stable solid composition comprising:
- a flowable self-solidifying cleaning composition pressed into a pressed solid and comprising less than 0.5 wt-% phosphorus-containing compounds comprising:
- up to about 15 wt-% water;
- about 20 wt-% to about 70 wt-% of an alkali metal carbonate;
- about 1 wt-% to about 40 wt-% of an alkali metal bicarbonate;
- about 1 wt-% to about 5 wt-% of a biodegradable aminocarboxylate selected from the group consisting of ethanoldiglycine, methylglycinediacetic acid, iminodisuccinic acid, N,N-bis (carboxylatomethyl)-L-glutamate, [S,S]-ethylenediaminedisuccinic acid (EDDS), 3-hydroxy-2,2′-iminodisuccinate (HIDS), and salt thereof.