Plurality of host materials, organic electroluminescent compound, and organic electroluminescent device comprising the same
OwnerJeong-Eun YANG, Ga-Won LEE +4inventors
InventorsJeong-Eun YANG, Ga-Won LEE, Hee-Ryong KANG, Sang-Hee CHO, Jeong-Hwan JEON, Hyo-Soon PARK
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Abstract
The present disclosure relates to a plurality of host materials, an organic electroluminescent compound, and an organic electroluminescent device. By comprising a plurality of host materials and/or an organic electroluminescent compound according to the present disclosure, an organic electroluminescent device can be provided which has low driving voltage and/or high luminous efficiency and/or long lifespan characteristics.
Claims16
A plurality of host materials comprising a first host material comprising a compound represented by the following Formula 1 and a second host material comprising a compound represented by the following Formula 2:
- wherein,
- X1 and Y1 each independently represent —N=, —NR7, —O—, or —S—;
- provided that any one of X1 and Y1 is —N=, and the other of X1 and Y1 is —NR7—, —O—, or —S—;
- R1 represents a substituted or unsubstituted (C6-C30)aryl or a substituted or unsubstituted (3- to 30-membered)heteroaryl;
- R2 to R4 and R7 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted fused ring of (C3-C30) aliphatic ring and (C6-C30) aromatic ring, or —L11N (Ar1)(Ar2);
- or may be linked to the adjacent substituents to form a ring(s);
- L1 and L11 each independently represent a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
- Ar1 and Ar2 each independently represent hydrogen, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C2-C30)alkenyl, a substituted or unsubstituted fused ring of (C3-C30) aliphatic ring and (C6-C30) aromatic ring, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3- to 30-membered)heteroaryl;
- R5 and R6 each independently represent a substituted or unsubstituted (C6-C30)aryl or a substituted or unsubstituted (3- to 30-membered)heteroaryl;
- and
- b and c each independently represent an integer of 1 or 2, d represents an integer of 1 to 4, and when b to d are an integer of 2 or more, each of R2 to R4 may be the same or different;
- wherein,
- ring A and ring B each independently represent a substituted or unsubstituted (C6-C30)arene or a substituted or unsubstituted (3- to 30-membered)heteroarene;
- R11 and R12 each independently represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3-to 30-membered)heteroaryl;
- or may be linked to each other to form a ring(s);
- X2 and Y2 each independently represent —N=, —NR24, —O—, or —S—;
- provided that any one of X2 and Y2 is —N=, and the other of X2 and Y2 is —NR24—, —O—, or —S—;
- R21 to R24 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted fused ring of (C3-C30) aliphatic ring and a (C6-C30) aromatic ring, or —L3-HAr;
- provided that at least one of R21 to R24 is —L3-HAr;
- L2 and L3 each independently represent a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
- HAr represents a substituted or unsubstituted (3- to 30-membered)heteroaryl containing at least one nitrogen atom;
- and
- n represents an integer of 1 to 4, m represents an integer of 1 to 8, and when n and m are an integer of 2 or more, each of R22 and R23 may be the same or different.
An organic electroluminescent compound represented by the following Formula 2′:
- wherein,
- ring A and ring B each independently represent a substituted or unsubstituted (C6-C30)arene or a substituted or unsubstituted (3- to 30-membered)heteroarene;
- R11 and R12 each independently represent a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, or a substituted or unsubstituted (3-to 30-membered)heteroaryl;
- or may be linked to each other to form a ring(s);
- X2 and Y2 each independently represent —N=, —NR24, —O—, or —S—;
- provided that any one of X2 and Y2 is —N=, and the other of X2 and Y2 is —NR24—, —O—, or —S—;
- R21 and R24 each independently represent hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted (C1-C30)alkyl, a substituted or unsubstituted (C6-C30)aryl, a substituted or unsubstituted (3- to 30-membered)heteroaryl, a substituted or unsubstituted (C3-C30)cycloalkyl, a substituted or unsubstituted (C1-C30)alkoxy, a substituted or unsubstituted tri(C1-C30)alkylsilyl, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30)arylsilyl, a substituted or unsubstituted (C1-C30)alkyldi(C6-C30)arylsilyl, a substituted or unsubstituted tri(C6-C30)arylsilyl, a substituted or unsubstituted fused ring of (C3-C30) aliphatic ring and a (C6-C30) aromatic ring, or —L3-HAr;
- provided that at least one of R21 to R24 is —L3-HAr, and if R23 is —L3-HAr, the case where ring A and ring B are both a substituted or unsubstituted benzene is excluded;
- L2 and L3 each independently represent a single bond, a substituted or unsubstituted (C6-C30)arylene, or a substituted or unsubstituted (3- to 30-membered)heteroarylene;
- HAr represents a substituted or unsubstituted (3- to 30-membered)heteroaryl containing at least one nitrogen atom;
- and
- n represents an integer of 1 to 4, m represents an integer of 1 to 8, and when n are m are an integer of 2 or more, each of R22 and R23 may be the same or different.
Dependencies are inferred from the claim text.