Etching method, method of manufacturing semiconductor device, nontransitory computer-readable recording medium and processing apparatus

Abstract

An etching technique removes a film by supplying a first gas containing a first halogen element and a second gas containing a second halogen element. In embodiments, the first gas includes a Group 13 halide and the second gas includes a chlorine-containing compound with a Group 16 element. The gases are introduced with different start times, optionally with a period of simultaneous supply, so the first gas weakens bonds in a nitride or oxide and the second gas accelerates removal. The method suits cleaning deposits from internal surfaces of a process vessel and etching films on a substrate. After etching, a cyclic purge removes residual species. A pre-coating step may form a nitride film to suppress diffusion of elements and stabilize initial film growth.

Dependencies are inferred from the claim text.