Self-healing polyurethane-based coating composition, polyurethane-based coating film including same, and methods of manufacturing the coating composition and the coating film

Abstract

A self-healing polyurethane-based coating composition, a polyurethane-based coating film including the same, and methods of manufacturing the coating composition and the coating film, in which design of an oligomer containing a disulfide functional group is capable of achieving self-healing performance at room temperature and ensuring appropriate fluidity, whereby a coating film can be manufactured by spraying. The composition further includes a polyisocyanate hardener, and the oligomer is formed by polymerizing a carbonate-type diol, an alicyclic isocyanate, and an aromatic disulfide-type diol. This specific molecular design provides high self-healing efficiency, enhanced optical transparency, and excellent mechanical stability. The coating film achieves a self-healing efficiency of 80% or more, a transmission rate of 85% or higher, and a sagging rate of 5% or less. The manufacturing process controls the molar ratios of hydroxyl (—OH) to isocyanate (—NCO) groups, optimizing cross-linking and ensuring durability in the final coating.

Dependencies are inferred from the claim text.