Water-soluble, biodegradable dihydroxyalkyl cellulose
AssigneeISP Investments Inc.
InventorsFangbin ZHOU, MICHAEL FRANZKE, Edward Di ANTONIO, Gijsbert KROON
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Abstract
The present application provides a water-soluble, partially biodegradable dihydroxyalkyl cellulose having about 0.7 to about 2.0 units of dihydroxyalkyl moiety per anhydroglucose moiety, having (i) a molecular weight of dihydroxyalkyl cellulose is in the range of from about 10,000 Daltons to about 1,500,000 Daltons, (ii) a biodegradation rate of ≥3% in an aquatic medium, and (iii) a water solubility at a threshold level of 2 g/L. Also discloses a method for preparing dihydroxyalkyl cellulose and functionalized dihydroxyalkyl cellulose compounds and their use in personal care applications.
Claims28
A water-soluble, partially biodegradable dihydroxyalkyl cellulose having about 0.7 to about 2.0 units of dihydroxyalkyl moiety per anhydroglucose moiety.
A method for preparing functionalized dihydroxyalkyl cellulose, comprising the steps of:
- a) mixing dihydroxyalkyl cellulose, isopropyl alcohol (IPA), water and caustic in a flask and stirring from about 0.1 hour to 1 hour to form swollen resultant;
- b) adding an aqueous solution of cationic, anionic, or hydrophobic agent to the resultant of (a) and heat the mixture to a temperature ranging from about 30° C. to 80° C. for about 1 to about 10 hours;
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- c) lowering the temperature of the resultant of (b) to a room temperature, neutralizing the resultant with acid, and washing with different strength of IPA, acetone, or methanol;
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- d) drying the resultant of step (c) in a temperature ranging from about 30° C. to about 80° C. to retrieve functionalized dihydroxyalkyl cellulose comprising cationic, anionic, or hydrophobic moieties.
A method for preparing hydrophobic functional dihydroxyalkyl cellulose. comprising the steps of:
- a) mixing from about 5% (w/w) to 45% (w/w) of dihydroxyalkyl cellulose, from about 20% (w/w) to 70% (w/w) of IPA, from about 5% (w/w) to 50% (w/w) of water and from about 1% (w/w) to 15% (w/w) of caustic in a flask and stirring from about 0.1 hour to 1 hour;
- b) adding from about 1% (w/w) to 30% (w/w) of cationic, anionic, or hydrophobic agent to the resultant of (a) and heat the mixture to a temperature ranging from about 30° C. to 120° C. for about 1 to about 16 hours;
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- c) lower the temperature of the resultant of (b) to room temperature, neutralize the resultant of step (b) with 50% (w/w) to 100% (w/w) of acid, and wash with different strength of 50% (w/w) to 100% (w/w) of IPA, acetone, or methanol;
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- d) dry the resultant of step (c) in temperature ranging from about 30° C. to about 80° C. in an oven to retrieve cationic, anionic, or hydrophobic functional dihydroxyalkyl cellulose.
Dependencies are inferred from the claim text.