Fluorinated polymer
AssigneeDaikin Industries, Ltd.
InventorsShun SHIBATA, lkuo YAMAMOTO, Masato KASHIWAGI, Michio MATSUDA, Masaki FUKUMORI, Daiki ISHII
Life of this patent
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Abstract
Provided is a fluorinated polymer having a repeating unit derived from a fluorinated monomer (f) having Rf1 or Rf2. In the fluorinated polymer, Rf1 represents —CF3, —CF2H, or —CFH2, Rf2 represents —CF2— or —CFH—, and each of Rf1 and Rf2 is not a portion of —CH2—CF2—CH2— or a fluoroalkyl group having 2 or more carbon atoms. Thus, a novel fluorinated polymer is provided.
Claims17
A water- and oil-repellent agent comprising a fluorine-containing polymer comprising a repeating unit derived from a fluorine-containing monomer (f) represented by the formula:
- wherein, independently at each occurrence,
- Xf is a hydrogen atom, a monovalent organic group or a halogen atom,
- Yf is a 1+α valent group composed of one or more selected from the group consisting of Yf1 and Yf2, but comprises at least one Yf2,
- Yf1 is a group composed of one or more selected from the group consisting of a direct bond, —O—, —C(═O)—, —C(═NR′)—, —S—, —S(═O)2—, —NR′—, —C(OR′)R′—, —C(OR′) (−)2 and —N(−)2, wherein R′ is a hydrogen atom or a monovalent organic group,
- Yf2 is a group composed of one or more selected from a divalent to tetravalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, a divalent to tetravalent hydrocarbon aromatic ring optionally having a substituent, and a divalent to tetravalent heterocyclic ring optionally having a substituent,
- Zf is Rf1, or a hydrocarbon group having 2 or more and 40 or less carbon atoms and including Rf1 or Rf2, and
- α is 1 to 3,
- wherein
- Rf1 is —CF3, —CF2H or —CFH2,
- Rf2 is —CF2— or —CFH—, and
- Rf1 and R12 do not constitute a moiety of a fluoroalkyl group having 2 or more carbon atoms or —CH2—CF2—CH2—.
Dependencies are inferred from the claim text.