Phosphorus-based flame retardant and thermoplastic resin composition including same
AssigneeLG Chem, Ltd.
InventorsSeoyoung IM, Hanbit JANG, Hoyong LEE
Life of this patent
Estimating the term…
Abstract
A phosphorus (P)-based flame retardant, a thermoplastic resin composition and a molded article including the phosphorus-based flame retardant are provided. The phosphorus-based flame retardant, even if an amount of use is reduced compared to a conventional flame retardant, is capable of providing significantly improved mechanical properties such as tensile strength and impact strength, while exhibiting excellent flame retardancy.
Claims20
A phosphorus-based flame retardant represented by the following Chemical Formula 1:
- wherein in Chemical Formula 1,
- R1 to R3 are the same as or different from each other, and are each independently selected from hydrogen, a hydroxyl group, a C1 to C40 alkyl group, a C2 to C40 alkenyl group, a C3 to C40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C6 to C60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms,
- R4 is selected from a C1 to C40 alkyl group, a C2 to C40 alkenyl group, a C3 to C40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C6 to C60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms, each of which comprises at least one substituent capable of forming coordination bonding with the following M,
- M is a metal selected from Group 1, Group 2, Group 3 and transition metals, or a protonated nitrogen base,
- m, n and x are each an integer in a range from 1 to 5, and
- wherein the C1 to C40 alkyl group, the C2 to C40 alkenyl group, the C3 to C40 cycloalkyl group, the heterocycloalkyl group having 3 to 40 nuclear atoms, the C6 to C60 aryl group and the heteroaryl group having 5 to 60 nuclear atoms of R1 to R4 are each independently unsubstituted or substituted with one or more substituents selected from deuterium (D), halogen, a cyano group, a nitro group, a hydroxyl group, an amine group, a carboxyl group, a C1 to C40 alkyl group, a C6 to C60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms, and when the substituents are plural in number, the substituents are the same as or different from each other.
The phosphorus-based flame retardant of clain 1, wherein the phosphorus-based flame retardant represented by Chemical Formula 1 comprises one or more selected from compounds represented by the following Chemical Formulas:
A phosphorus-based flame retardant represented by the following Chemical Formula 2:
- wherein in Chemical Formula 2,
- R1 to R3 are the same as or different from each other, and are each independently being selected from hydrogen, a hydroxyl group, a C1 to C40 alkyl group, a C2 to C40 alkenyl group, a C3 to C40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C6 to C60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms,
- R4 is selected from a C1 to C40 alkyl group, a C2 to C40 alkenyl group, a C3 to C40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C6 to C60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms,
- R3 and R4 are bonded with each other to form a monocyclic or polycyclic condensed ring,
- M is a metal selected from Group 1, Group 2, Group 3 and transition metals, or a protonated nitrogen base,
- m, n and x are each an integer in a range from 1 to 5, and
- the C1 to C40 alkyl group, the C2 to C40 alkenyl group, the C3 to C40 cycloalkyl group, the heterocycloalkyl group having 3 to 40 nuclear atoms, the C6 to C60 aryl group and the heteroaryl group having 5 to 60 nuclear atoms of R1 to R4 are each independently unsubstituted or substituted with one or more substituents selected from deuterium (D), halogen, a cyano group, a nitro group, a hydroxyl group, an amine group, a carboxyl group, a C1 to C40 alkyl group, a C6 to C60 aryl group, and a heteroaryl group having 5 to 60 nuclear atoms, and when the substituents are plural in number, the substituents are the same as or different from each other.
Dependencies are inferred from the claim text.