# US 2025/0146110 A1 · Method for manufacturing grain-oriented electrical steel sheet, and grain-oriented electrical steel sheet > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2025/0146110 A1 - Document ID: US20250146110A1 - Status: Published application - Kind: A1 - Application number: 18/697,730 - Filed: 2022-10-31 - Published: 2025-05-08 - Earliest claimed: 2021-10-29 - Assignees: Jfe Steel Corporation - Applicants: Jfe Steel Corporation - Inventors: Shigehiro TAKAJO; Ryota HOSOYA; Hiroi YAMAGUCHI - Web page: https://patentgrep.com/patent/US20250146110A1 ## CPC - C22C 38/02: containing silicon - H01F 1/147: Alloys characterised by their composition {(treatment thereof for enhancing their electromagnetic properties C21D8/12)} - C21D 1/42: Induction heating - C21D 6/008: {containing Si} - C21D 8/1222: {Hot rolling} - C21D 8/1233: {Cold rolling} - C21D 8/1261: {following hot rolling} - C21D 8/1272: {Final recrystallisation annealing} - C21D 8/1283: {Application of a separating or insulating coating} - C21D 9/46: for sheet metals - C22C 38/001: {containing N} - C22C 38/002: {containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60} - C22C 38/04: containing manganese - C22C 38/06: containing aluminium - C22C 38/60: containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur - H01F 1/16: in the form of sheets (H01F1/147 takes precedence) - C21D 2201/05: Grain orientation - Y02P 10/25: Process efficiency - C22C: ALLOYS (treatment of alloys C21D, C22F) - H01F: MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES - C21D: MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass C23F17/00; unidirectional solidification of eutectic materials or unidirectional demixing of eutectoid materials C30B) - Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS ## Abstract This disclosure discloses a method for manufacturing a grain-oriented electrical steel sheet and a grain-oriented electrical steel sheet manufactured by the method. The method comprises heating a slab having a predetermined composition by induction heating in a frequency range of 20 to 1000 Hz under predetermined conditions, where the average current flowing in the coil is monotonically decreased as time passes during slab heating; subjecting the slab to finish rolling performed with the rolling finish temperature set to 950° C. or lower at one or both of the leading or trailing end; soaking the hot-rolled sheet at 750° C. or higher for 5 to 90 seconds to obtain a hot band annealed sheet; then cold rolling the annealed sheet once, or twice or more with intermediate annealing performed therebetween to obtain a cold-rolled sheet having a final sheet thickness; and subjecting the cold-rolled sheet to primary and secondary recrystallization annealings. ## Claims ### Claim 1 A method for manufacturing a grain-oriented electrical steel sheet comprising: heating a steel slab to a slab extraction temperature Tr (° C.) of 1380° C. or lower by induction heating and holding the steel slab at a temperature T satisfying a range of Tr−10° C.≤T≤Tr+10° C. for at least 5 minutes, the steel slab containing C: 0.030 mass % to 0.085 mass %, Si: 2.00 mass % to 4.50 mass %, Mn: 0.03 mass % to 0.50 mass %, S: 0.0005 mass % to 0.0300 mass %, sol.Al: 0.005 mass % or more and less than 0.025 mass %, N: 0.0030 mass % to 0.0090 mass %, and at least one element selected from the group consisting of P, As, and Sb: 0.005 mass % to 0.500 mass %, where sol.Al/N satisfies 1.7 or more and 3.0 or less, with the balance being Fe and inevitable impurities, wherein, an average current value flowing through the slab is monotonically decreased as heating time passes, and the induction heating is performed with a frequency of 20 Hz to 1000 Hz, subjecting the slab to finish rolling to obtain a hot-rolled sheet, wherein a rolling finish temperature at one or both of a leading or trailing end of the hot-rolled sheet is set to 950° C. or lower, subjecting the hot-rolled sheet to hot band annealing with soaking at a temperature of 750° C. or higher and 1170° C. or lower for 5 seconds or more and 90 seconds or less to obtain a hot band annealed sheet, subsequently, cold rolling the hot band annealed sheet once, or twice or more with intermediate annealing performed therebetween to obtain a cold-rolled sheet with a final sheet thickness, and subjecting the cold-rolled sheet to primary recrystallization annealing followed by secondary recrystallization annealing. ### Claim 2 (depends on 1) The method for manufacturing a grain-oriented electrical steel sheet according to claim 1, wherein the steel slab further contains at least one selected from the group consisting of Se: 0.0005 mass % to 0.0200 mass %, Ni: 0.01 mass % to 1.50 mass %, Cr: 0.03 mass % to 0.50 mass %, Cu: 0.03 mass % to 0.50 mass %, Sn: 0.005 mass % to 0.500 mass %, Bi: 0.005 mass % to 0.500 mass %, Mo: 0.005 mass % to 0.100 mass %, B: 0.0002 mass % to 0.0025 mass %, Te: 0.0005 mass % to 0.0100 mass %, Zr: 0.001 mass % to 0.010 mass %, Nb: 0.001 mass % to 0.010 mass %, V: 0.001 mass % to 0.010 mass %, and Ta: 0.001 mass % to 0.010 mass %. ### Claim 3 (depends on 1) The method for manufacturing a grain-oriented electrical steel sheet according to claim 1, wherein the steel slab contains at least two elements selected from the group consisting of Sb, As, and P in an amount of 0.001 mass % to 0.100 mass % each. ### Claim 4 (depends on 1) The method for manufacturing a grain-oriented electrical steel sheet according to claim 1, wherein in heating the steel slab, the frequency of induction heating at heating end time is set to be higher than the frequency at heating start time and is not decreased during heating. ### Claim 5 (depends on 1) The method for manufacturing a grain-oriented electrical steel sheet according to claim 1, wherein in obtaining the hot band annealed sheet, the hot-rolled sheet is further held at a temperature of 700° C. or higher and 900° C. or lower for 5 seconds or more and 180 seconds or less. ### Claim 6 (depends on 1) The method for manufacturing a grain-oriented electrical steel sheet according to claim 1, wherein the heating temperature of the steel slab is 1350° C. or lower. ### Claim 7 (depends on 1) The method for manufacturing a grain-oriented electrical steel sheet according to claim 1, wherein a coil edge of 5 mm or more is cut and removed prior to the first cold rolling applied to the hot band annealed sheet. ### Claim 8 A grain-oriented electrical steel sheet comprising, a chemical composition containing, by mass %, Si: 2.00 mass % to 4.50 mass %, Mn: 0.03 mass % to 0.50 mass %, and at least one element selected from the group consisting of Sb, As, and P: 0.005 mass % to 0.100 mass %, with the balance being Fe and inevitable impurities, a magnetic flux density B8 of 1.94 T or more, and a sheet thickness of 0.35 mm or less, wherein a number of rough edges (edge cracks) exceeding 3 cm in a sheet transverse direction on an edge portion is 0.020 or less per 10 m in length of the steel sheet. ### Claim 9 (depends on 8) The grain-oriented electrical steel sheet according to claim 8, wherein the chemical composition further contains at least one selected from the group consisting of: Ni: 0.01 mass % to 1.50 mass %, Cr: 0.03 mass % to 0.50 mass %, Cu: 0.03 mass % to 0.50 mass %, Sn: 0.005 mass % to 0.500 mass %, Bi: 0.005 mass % to 0.500 mass %, Mo: 0.005 mass % to 0.100 mass %, B: 0.0002 mass % to 0.0025 mass %, Te: 0.0005 mass % to 0.0100 mass %, Zr: 0.001 mass % to 0.010 mass %, Nb: 0.001 mass % to 0.010 mass %, V: 0.001 mass % to 0.010 mass %, and Ta: 0.001 mass % to 0.010 mass %. ### Claim 10 (depends on 8) The grain-oriented electrical steel sheet according to claim 8, wherein the chemical composition contains at least two elements selected from the group consisting of Sb, As, and P in an amount of 0.001 mass % to 0.100 mass % each. ### Claim 11 (depends on 2) The method for manufacturing a grain-oriented electrical steel sheet according to claim 2, wherein the steel slab contains at least two elements selected from the group consisting of Sb, As, and P in an amount of 0.001 mass % to 0.100 mass % each. ### Claim 12 (depends on 2) The method for manufacturing a grain-oriented electrical steel sheet according to claim 2, wherein in heating the steel slab, the frequency of induction heating at heating end time is set to be higher than the frequency at heating start time and is not decreased during heating. ### Claim 13 (depends on 2) The method for manufacturing a grain-oriented electrical steel sheet according to claim 2, wherein in obtaining the hot band annealed sheet, the hot-rolled sheet is further held at a temperature of 700° C. or higher and 900° C. or lower for 5 seconds or more and 180 seconds or less. ### Claim 14 (depends on 2) The method for manufacturing a grain-oriented electrical steel sheet according to claim 2, wherein the heating temperature of the steel slab is 1350° C. or lower. ### Claim 15 (depends on 2) The method for manufacturing a grain-oriented electrical steel sheet according to claim 2, wherein a coil edge of 5 mm or more is cut and removed prior to the first cold rolling applied to the hot band annealed sheet. ### Claim 16 (depends on 9) The grain-oriented electrical steel sheet according to claim 9, wherein the chemical composition contains at least two elements selected from the group consisting of Sb, As, and P in an amount of 0.001 mass % to 0.100 mass % each.