Biobased, eco-friendly hotmelt adhesive
AssigneeThüringisches Institut für Textil-und Kunststoff-Forschung E.V.
InventorAndreas KRYPCZYK
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Abstract
The invention describes an eco-friendly hotmelt adhesive based on renewable raw materials. The hotmelt adhesive formulation is made up of biobased polyesters, specifically a combination of polylactide and polybutylene succinate, and also of resins, plasticizers and stabilizers; further additives may optionally be added as well, for example waxes, fumed silica, lime or color pigments. The raw materials used are sustainable, biodegradable and unhazardous to nature. The adhesive exhibits very good adhesion to wood, paper, cardboard and certain, predominantly non-polar plastics such as PMMA, ABS, PC, PLA or PET and can be applied with the commonplace systems.
Claims16
A hotmelt adhesive formulation comprising:
- at least one polylactide having a glass transition temperature of more than 50° C., a melt flow index of more than 25 g/10 min, measured at a temperature of 210° C. with a load of 2.16 kg, a weight-average molecular weight Mw in the range from 120 000 to 280 000 g/mol and a Hansen solubility parameter of 19.2 to 21.1 (J/cm3)0.5, with the fraction of the at least one polylactide being 5 to 45% by weight, based on the total weight of the hotmelt adhesive formulation;
- at least one polybutylene succinate having a melt flow index of 3 to 26 g/10 min, measured at 190° C. with a load of 2.16 kg, a weight-average molecular weight Mw in the range from 60 000 to 190 000 g/mol and a Hansen solubility parameter of 20.1 to 21.2 (J/cm3)0.5, with the fraction of the at least one polybutylene succinate being 10 to 55% by weight, based on the total weight of the hotmelt adhesive formulation;
- at least one naturally occurring resin having a melting temperature between 6° and 150° C., a melt viscosity of 80 to 24 000 mPa·s at 140° C. and a Hansen solubility parameter between 16.0 and 21 (J/cm3)0.5, with the fraction of the at least one naturally occurring resin being 30 to 55% by weight, based on the weight of the hotmelt adhesive formulation;
- at least one citric acid tri (C2-C8)alkyl ester or acetylcitric acid tri (C2-C8)alkyl ester as plasticizer in a fraction of 5 to 15% by weight, based on the total weight of the hotmelt adhesive formulation;
- and
- at least one epoxidized vegetable oil as stabilizer in a fraction of 0.5 to 1.5% by weight, based on the total weight of the hotmelt adhesive formulation.
Dependencies are inferred from the claim text.