High molecular weight polyesteramides
AssigneeSolutia Inc.
InventorsARISTOTELIS KARAGIANNIS, PINGUAN ZHENG, SCOTT ELLERY GEORGE, OLIVIER ETIENNE HILAIRE GEERT VERKINDEREN, KIM NAZ ROSEMARIE DUMOLEIJN, JOSHUA SETH CANNON, PU ZHANG, KHANH DUC TRAN
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Abstract
The invention provides certain polyesteramide compositions which have glass transition temperatures (Tg) of greater than or equal to 0° C. The polyesteramides of the invention are useful as polymeric interlayers for laminate structures, for example, safety glass, where excellent toughness is combined with high adhesion to glass.
Claims19
A polyesteramide composition comprising residues of:
- a. at least one diacid;
- b. about 10 to about 90 mole percent of a diol;
- c. about 10 to about 90 mole percent of a diamine;
- and optionally
- d. a multifunctional reactant having at least three functional groups chosen from carboxylic acid, amine, and hydroxyl groups;
- wherein the sum of diacid equivalents is about 100 mole percent and the sum of diol and diamine equivalents is about 100 mole percent;
- and
- e. about 0.01 to about 10 weight percent, based on the total weight of the polyesteramide comprised of a., b., c., and optionally d., of a chain extender reactive with groups chosen from carboxyl, amino, and hydroxyl groups,
- and wherein said polyesteramide exhibits an inherent viscosity of about 0.6 to about 2.0 dL/g.
A polyesteramide composition comprising residues of:
- a. a diacid chosen from sebacic acid and dodecanedioic acid;
- b. about 40 to about 60 mole percent of 1,4-cyclohexanedimethanol;
- c. about 40 to about 60 mole percent of 4,4′-methylenebis(2-methylcyclohexylamine);
- and
- d. about 0.1 to about 0.5 mole percent of trimethylolpropane;
- wherein the sum of diacid equivalents is about 100 mole percent and the sum of diol and diamine equivalents is about 100 mole percent;
- and
- e. about 0.01 to about 10 weight percent, based on the total weight of the polyesteramide comprised of a., b., c., and optionally d., of a chain extender reactive with groups chosen from carboxyl, amino, and hydroxyl groups.
A multiple layer interlayer comprising:
- a first layer comprising a polyesteramide composition comprising residues of:
- a. at least one diacid;
- b. about 10 to about 90 mole percent of a diol;
- c. about 10 to about 90 mole percent of a diamine;
- and optionally
- d. a multifunctional reactant having at least three functional groups chosen from carboxylic acid, amine, and hydroxyl groups;
- wherein the sum of diacid equivalents is about 100 mole percent and the sum of diol and diamine equivalents is about 100 mole percent;
- and
- e. about 0.01 to about 10 weight percent, based on the total weight of the polyesteramide composition comprised of a., b., c., and optionally d., of a chain extender reactive with groups chosen from carboxyl, amino, and hydroxyl groups,
- wherein said polyesteramide exhibits an inherent viscosity of about 0.6 to about 2.0 dL/g;
- and
- a second layer comprising a polymer composition which is different than the polyesteramide composition of the first layer.
A laminate structure, comprising:
- a. a top panel layer;
- b. a polyesteramide composition comprising residues of:
- i. at least one diacid;
- ii. about 10 to about 90 mole percent of a diol;
- iii. about 10 to about 90 mole percent of a diamine;
- and optionally
- iv. a multifunctional reactant having at least three functional groups chosen from carboxylic acid, amine, and hydroxyl groups;
- wherein the sum of diacid equivalents is about 100 mole percent and the sum of diol and diamine equivalents is about 100 mole percent;
- and
- v. about 0.01 to about 10 weight percent, based on the total weight of the polyesteramide composition comprised of i., ii., iii., and optionally iv., of a chain extender reactive with groups chosen from carboxyl, amino, and hydroxyl groups, wherein said polyesteramide exhibits an inherent viscosity of about 0.6 to about 2.0 dL/g;
- and optionally
- c. a bottom panel layer.
Dependencies are inferred from the claim text.