# US 2025/0093293 A1 · Gas sensor > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2025/0093293 A1 - Document ID: US20250093293A1 - Status: Published application - Kind: A1 - Application number: 18/961,877 - Filed: 2024-11-27 - Published: 2025-03-20 - Earliest claimed: 2022-06-22 - Assignees: NGK Insulators, Ltd. - Applicants: Ngk Insulators, Ltd. - Inventors: Yusuke WATANABE - Web page: https://patentgrep.com/patent/US20250093293A1 ## CPC - G01N 27/41: Oxygen pumping cells - G01N 27/419: Measuring voltages or currents with a combination of oxygen pumping cells and oxygen concentration cells - G01N 33/0027: {concerning the detector} - G01N 27/4065: {Circuit arrangements specially adapted therefor} - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) ## Abstract A gas sensor includes a sensor element and a control unit thereof. The sensor element includes: a base part; a measurement-object gas flow cavity; a reference gas chamber separated from the measurement-object gas flow cavity and closed inside the base part; a reference electrode disposed in the reference gas chamber; and a pump electrode disposed at a position different from the reference gas chamber. The control unit includes: a storing part storing in advance, a required amount of oxygen to be present in the reference gas chamber at a time at which oxygen concentration in the reference gas chamber is a predetermined concentration; and a processing part performing refresh processing in which a current is applied between the pump electrode and the reference electrode to pump out oxygen from the reference gas chamber, and then pump oxygen into the reference gas chamber in the required amount of the oxygen. ## Claims ### Claim 1 A gas sensor for detecting a target gas to be measured in a measurement-object gas, the gas sensor comprising a sensor element and a control unit for controlling the sensor element, wherein the sensor element comprises: a base part in an elongated plate shape, including an oxygen-ion-conductive solid electrolyte layer; a measurement-object gas flow cavity for introduction and flow of a measurement-object gas, formed from one end part in a longitudinal direction of the base part; a reference gas chamber formed inside the base part, and being separated from the measurement-object gas flow cavity and closed inside the base part; a reference electrode disposed in the reference gas chamber; and a pump electrode disposed at a position different from the reference gas chamber, and the control unit comprises: a storing part storing in advance, a required amount of oxygen to be present in the reference gas chamber at a time at which oxygen concentration in a reference gas in the reference gas chamber is a predetermined concentration; and a processing part performing refresh processing in which a current is applied between the pump electrode and the reference electrode to pump out oxygen present in the reference gas chamber from the reference gas chamber, and then pump oxygen into the reference gas chamber in the required amount of the oxygen which is stored in advance by the storing part. ### Claim 2 (depends on 1) The gas sensor according to claim 1, wherein the storing part stores in advance, as the required amount of the oxygen, a required current integrated value of a current flowing between the pump electrode and the reference electrode when the current is applied between the pump electrode and the reference electrode to move oxygen of the required amount of the oxygen, and in the refresh processing, the processing part pumps out oxygen present in the reference gas chamber from the reference gas chamber, and then applies the current between the pump electrode and the reference electrode until an integrated value of the current flowing between the pump electrode and the reference electrode reaches the required current integrated value to pump oxygen into the reference gas chamber in the required amount of the oxygen. ### Claim 3 (depends on 1) The gas sensor according to claim 1, wherein the storing part stores in advance, as the required amount of the oxygen, a required time when a predetermined current is applied between the pump electrode and the reference electrode to move oxygen of the required amount of the oxygen, and in the refresh processing, the processing part pumps out oxygen present in the reference gas chamber from the reference gas chamber, and then applies the predetermined current between the pump electrode and the reference electrode for the required time to pump oxygen into the reference gas chamber in the required amount of the oxygen. ### Claim 4 (depends on 1) The gas sensor according to claim 1, wherein the storing part stores in advance, as the required amount of the oxygen, a required current value when a current is applied between the pump electrode and the reference electrode for a predetermined time to move oxygen of the required amount of the oxygen, and in the refresh processing, the processing part pumps out oxygen present in the reference gas chamber from the reference gas chamber, and then applies the current of the required current value between the pump electrode and the reference electrode for the predetermined time to pump oxygen into the reference gas chamber in the required amount of the oxygen. ### Claim 5 (depends on 1) The gas sensor according to claim 1, wherein in the refresh processing, the processing part applies a predetermined voltage between the pump electrode and the reference electrode to make the current flow, and pumps out oxygen present in the reference gas chamber from the reference gas chamber until the current becomes at a predetermined value or less. ### Claim 6 (depends on 1) The gas sensor according to claim 1, wherein in the refresh processing, the processing part applies a predetermined voltage between the pump electrode and the reference electrode to make the current flow, and pumps out oxygen present in the reference gas chamber from the reference gas chamber until a change amount per time in the current becomes at a predetermined value or less. ### Claim 7 (depends on 1) The gas sensor according to claim 1, wherein a cycle for performing the refresh processing is determined based on a volume of the reference gas chamber.