Light emitting element, ink composition and display device including the light emitting element
AssigneeSamsung Display Co., Ltd.
InventorsYUNKU JUNG, SOOHO LEE, Jungho JO, Chang Yeol HAN, YUNHYUK KO, SEHUN KIM
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Abstract
A light emitting element of an embodiment includes a first electrode, a hole transport region on the first electrode, an emission layer on the hole transport region, an electron transport region on the emission layer, and a second electrode on the electron transport region, the electron transport region includes a nanoparticle including a nanoparticle core and a ligand, the nanoparticle core includes a core compound represented by Formula 1, and the ligand is bonded to the surface of the nanoparticle core and represented by Formula 2 or Formula 3.
Claims20
A light emitting element, comprising:
- a first electrode;
- a hole transport region on the first electrode;
- an emission layer on the hole transport region;
- an electron transport region on the emission layer;
- and
- a second electrode on the electron transport region,
- wherein the electron transport region comprises a nanoparticle comprising a nanoparticle core, and a ligand,
- the nanoparticle core comprises a core compound represented by the following Formula 1, and
- the ligand is bonded to the surface of the nanoparticle core, and represented by the following Formula 2 or Formula 3:
- in Formula 1,
- A is Zn, or Sn, and
- “x”, and “y” are each independently an integer of 1 to 5, in Formula 2,
- M is one among Li, Na, K, Rb, Cs, Be, Ca, Sr, and Ba,
- R1 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- “a” is an integer of 0 to 3, and
- “”, and
- are each a position connected with the nanoparticle core, and
- in Formula 3,
- R2 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- M is the same as defined with respect to Formula 2,
- “b” is an integer of 0 to 3, and
- “” is a position connected with the nanoparticle core.
An ink composition comprising:
- a nanoparticle core comprising a core compound represented by the following Formula 1;
- a preliminary ligand represented by the following Formula 4;
- and
- a solvent in which the nanoparticle core and the preliminary ligand are dispersed:
- in Formula 1,
- A is Zn, or Sn, and
- “x”, and “y” are each independently an integer of 1 to 5,
- in Formula 4,
- M is one among Li, Na, K, Rb, Cs, Be, Ca, Sr, and Ba,
- R3 and R4 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms, and
- “c” and “d” are each independently an integer of 0 to 3.
A display device comprising:
- a base layer;
- a circuit layer on the base layer;
- and
- a display element layer on the circuit layer and comprising a light emitting element,
- wherein:
- the light emitting element comprises a first electrode, a second electrode on the first electrode, and an electron transport region between the first electrode and the second electrode,
- the electron transport region comprises a nanoparticle comprising a nanoparticle core, and a ligand,
- the nanoparticle core comprises a core compound represented by the following Formula 1, and
- the ligand is bonded to the surface of the nanoparticle core and represented by the following Formula 2 or Formula 3:
- in Formula 1,
- A is Zn, or Sn, and
- “x”, and “y” are each independently an integer of 1 to 5, in Formula 2,
- M is one among Li, Na, K, Rb, Cs, Be, Ca, Sr, and Ba,
- R1 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- “a” is an integer of 0 to 3, and
- “”, and
- are each a position connected with the nanoparticle core, and
- in Formula 3,
- R2 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group of 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms, a substituted or unsubstituted aryl group of 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 30 ring-forming carbon atoms,
- M is the same as defined with respect to Formula 2,
- “b” is an integer of 0 to 3, and
- “” is a position connected with the nanoparticle core.
Dependencies are inferred from the claim text.