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US 2025/0042875 A1Published application
Pesticidally active pyridazinone compounds
AssigneeSyngenta Crop Protection AG
InventorsJagadeesh Prathap KILARU, Mangala PHADTE, Simone BERARDOZZI, Roger Graham HALL, André JEANGUENAT, Thomas PITTERNA, Matthias WEISS, Michel MUEHLEBACH, Myriem EL QACEMI
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Abstract
Compounds of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.
Claims16
A compound of the formula (I)
- wherein:
- Q is
- where the staggered line represents the connection of Q to the rest of compound of the formula (I);
- A is N or CRY;
- R1 is hydrogen, C1-C6alkyl, C1-C6cyanoalkyl, aminocarbonylC1-C6alkyl, hydroxycarbonylC1-C6alkyl, C1-C6nitroalkyl, trimethylsilaneC1-C6alkyl, C1-C3alkoxy-C1-C6alkyl, C1-C6haloalkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, C3-C4cycloalkyl-C1-C2alkyl, C3-C4cycloalkyl-C1-C2alkyl wherein the C3-C4cycloalkyl group is substituted with 1 or 2 halogen atoms, oxetan-3-yl-CH2—, C1-C6alkylcarbonyl, C1-C6alkoxycarbonyl, phenyloxycarbonyl, benzyloxycarbonyl, benzyl, or benzyl substituted with 1 to 3 substituents independently selected from halogen, C1-C6alkoxy and C1-C6haloalkyl;
- R2a and R2b are independently selected from hydrogen, C1-C3alkyl, C1-C3haloalkyl, C1C3haloalkylsuflanyl, C1-C3alkoxy, C1-C3haloalkoxy, halogen, NO2, SF5, CN, C(O)NH2, C(O)OH, C(S)NH2, C3-C6cycloalkyl, C3-C6cycloalkyl substituted with one to three substituents independently selected from RX;
- C1-C6cycloalkylcarbonyl, phenyl, phenyl substituted with one to three substituents independently selected from RX;
- heteroaryl, heteroaryl substituted with one to three substituents independently selected from RX;
- OR6, piperidin-2-one-1-yl, piperidin-2-one-1-yl substituted with one to two substituents independently selected from RX;
- pyridin-2-one-1-yl, pyridin-2-one-1-yl substituted with one to two substituents independently selected from RX;
- azetidin-1-yl, azetidin-1-yl substituted with one to two substituents independently selected from RX;
- pyrrolidin-1-yl, pyrrolidin-1-yl substituted with one to two substituents independently selected from RX;
- C3-C6cycloalkyl-C1C4alkyl, C3-C6cycloalkyl-C1-C4alkyl substituted with one to two substituents independently selected from RZ;
- C3-C6cycloalkyl-C1-C3alkoxy, C3-C6cycloalkyl-C1-C3alkoxy substituted with one to two substituents independently selected from RX;
- C1-C5cyanoalkyl, C1-C5cyanoalkoxy, C1-C4alkylsulfanyl, C1-C4alkylsulfanyl substituted with one to three substituents independently selected from RX;
- C1C4alkylsulfonyl, C1-C4alkylsulfonyl substituted with one to three substituents independently selected from RX;
- C1-C4alkylsulfinyl, and C1-C4alkylsulfinyl substituted with one to three substituents independently selected from RX;
- R3 is C1-C3alkyl or C1-C3haloalkyl;
- R4 is
- where the staggered line represents the connection of R4 to Qa or Qb;
- A1, A2, and A3 are, independently of each other, N or CH;
- R4c is C1-C3alkyl, C1-C3haloalkyl, allyl, propargyl, or C3-C6cycloalkylC1-C4alkyl;
- R5 is hydrogen, C1-C3alkyl, C1-C3haloalkyl, C3-C4cycloalkyl, C1-C3alkoxy, C3-C4alkoxyC(O)—, (C1-C3alkoxy)2CH—, halogen, —CN, NH2C(O)—, amino (i.e —NH2), (C1-C3alkyl)amino, di(C1-C3alkyl)amino, hydroxy, C3-C4halocycloalkyl, C3-C4cyanocycloalkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, C1-C4haloalkylsulfanyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C3alkoxy-C1-C3alkyl, C1-C3alkoxy-C1-C3alkoxy-C1-C3alkyl, (C1-C3alkyl)sulfonylamino, (C1-C3alkyl)sulfonyl(C1-C3alkyl)amino, (C1-C3alkyl)NHC(O)—, (C1-C3alkyl)2NC(O)—, (C3-C4cycloalkyl)NHC(O)—, (C3-C4cycloalkyl)(C1-C3alkyl)NC(O)—, (C1-C3alkyl)C(O)(C1-C3alkyl)N—, (C1-C3alkyl)C(O)NH—, (C1-C3alkyl)C(O)—, (C1-C3alkoxy)C(O)—, HC(O)—, diphenylmethanimine, C1-C3haloalkoxy, phenyl, or a 5-membered heteroaromatic ring;
- or
- R5 is phenyl substituted with one to three substituents selected from C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy, C3-C4cycloalkyl, halogen, —CN and hydroxyl;
- or
- R5 is a 5-membered heteroaromatic ring substituted with one to three substituents selected from C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy, C3-C4cycloalkyl, halogen, —CN and hydroxyl;
- R5a and R5b are, independently of each other, selected from hydrogen, halogen, —CN, C1-C3alkyl, C1-C3haloalkyl, C3-C4cycloalkyl, C1-C3alkoxy, and C1-C3haloalkoxy;
- R6 is phenyl, benzyl, heteroaryl, or C3-C6cycloalkyl;
- or
- R6 is phenyl, benzyl, heteroaryl, or C3-C6cycloalkyl, each of which, independently of each other, is substituted with one to three substituents independently selected from RX;
- RX is independently selected from halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy, C1-C3haloalkoxy, NO2, SF5, CN, —C(O)NH2, —C(S)NH2, C1-C4haloalkylsulfanyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, C1-C4alkylsulfanyl, C1-C4alkylsulfinyl and C1-C4alkylsulfonyl;
- RY is selected from hydrogen, C1-C3 alkyl, C1-C3haloalkyl, hydroxy, C1-C3alkoxy, C1-C3haloalkoxy, halogen, —CN and cyclopropyl;
- RZ is selected from oxo, halogen, C1-C3alkyl, C1-C3haloalkyl, C1-C3alkoxy, C1-C3haloalkoxy and CN;
- X0 is O or S;
- and
- an agrochemically acceptable salt, stereoisomer, enantiomer, tautomer and N-oxide of the compound of formula I.
34 more elements
Dependencies are inferred from the claim text.