Back to results
US 2025/0034471 A1Published application
Gasoline additive composition for improved engine performance
AssigneeAfton Chemical Corporation
InventorsJanice Jianzhao Wang, Julienne Galante-Fox
Life of this patent
Estimating the term…
Abstract
The present disclosure provides fuel additives including Mannich detergent additive(s) and succinimide detergent additive(s) effective to improve engine performance in both port fuel injected and gasoline direct injection engines.
Claims32
A gasoline fuel composition comprising a fuel additive for a spark-ignition engine, the fuel additive comprising:
- a Mannich detergent derived from the reaction product of a hydrocarbyl-substituted phenol or cresol, one or more aldehydes, and one or more alkylene polyamines;
- a succinimide detergent prepared by reacting a hydrocarbyl-substituted succinic acylating agent with an amine, polyamine, or alkyl amine having one or more primary, secondary, or tertiary amino groups;
- wherein a weight ratio of the Mannich detergent to the succinimide detergent is from about 20:1 to about 30:1;
- wherein the Mannich detergent has the structure of Formula I:
- wherein R1 is hydrogen or a C1 to C4 alkyl group, R2 is a hydrocarbyl group having a molecular weight of about 500 to about 3000, R3 is a C1 to C4 alkylene or alkenyl group, and R4 is hydrogen, and R5 is a mono or di(C1 to C4)alkyl amino C1-C12 alkyl group;
- wherein the succinimide detergent is a hydrocarbyl substituted mono-succinimide detergent, a hydrocarbyl substituted bis-succinimide detergent, or a combination thereof;
- and
- wherein the hydrocarbyl-substituted succinic acylating agent is a hydrocarbyl-substituted succinic anhydride, wherein the hydrocarbyl group has a molecular weight of about 450 to about 3000, and wherein a molar ratio of the hydrocarbyl-substituted succinic anhydride to the amine, polyamine, or alkyl amine is from about 0.5:1 to about 2:1;
- and
- wherein the gasoline fuel composition includes about 55 to about 190 ppmw of the Mannich detergent, about 0.5 to about 20 ppmw of the succinimide detergent;
- and about 5 to about 150 ppmw of the alkoxylated alcohol.
8 more elements
(canceled)
(canceled)
(canceled)
(canceled)
(canceled)
A method of reducing deposits in a gasoline engine, the method comprising:
- operating a gasoline engine on a fuel composition containing a major amount of a gasoline fuel and a minor amount of a fuel additive by injecting the gasoline fuel through one or more injectors;
- wherein the fuel additive includes (i) a Mannich detergent derived from the reaction product of a hydrocarbyl-substituted phenol or cresol, one or more aldehydes, and one or more alkylene polyamines;
- (ii) a succinimide detergent prepared by reacting a hydrocarbyl-substituted succinic acylating agent with an amine, polyamine, or alkyl amine having one or more primary, secondary, or tertiary amino groups;
- and (iii) wherein the fuel additive has a weight ratio of the Mannich detergent to the succinimide detergent of from about 20:1 to about 30:1;
- wherein the fuel additive reduces deposits in the gasoline engine;
- and
- wherein the Mannich detergent has the structure of Formula I:
- wherein R1 is hydrogen or a C1 to C4 alkyl group, R2 is a hydrocarbyl group having a molecular weight of about 500 to about 3000, R3 is a C1 to C4 alkylene or alkenyl group, and R4 is hydrogen, and R5 is a mono or di(C1 to C4)alkyl amino C1-C12 alkyl group;
- wherein the succinimide detergent is a hydrocarbyl substituted mono-succinimide detergent, a hydrocarbyl substituted bis-succinimide detergent, or a combination thereof;
- and wherein the hydrocarbyl-substituted succinic acylating agent is a hydrocarbyl-substituted succinic anhydride, wherein the hydrocarbyl group has a molecular weight of about 450 to about 3000, and wherein a molar ratio of the hydrocarbyl-substituted succinic anhydride to the amine, polyamine, or alkyl amine is from about 0.5:1 to about 2:1;
- and
- wherein the gasoline fuel composition includes about 55 to about 190 ppmw of the Mannich detergent, about 0.5 to about 20 ppmw of the succinimide detergent;
- and about 5 to about 150 ppmw of the alkoxylated alcohol.
10 more elements
(canceled)
(canceled)
(canceled)
(canceled)
Dependencies are inferred from the claim text.