Bicyclic Compounds for the Control of Invertebrate Pests

A compound of formula I

• wherein
• R1 is C1-C6-alkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy-C1-C4-alkyl, C1-C6-alkoxy-C1-C4-alkoxy, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, or C3-C6-cycloalkoxy-C1-C4-alkyl, which are unsubstituted or halogenated;
• phenyl or benzyl, wherein the rings are unsubstituted or substituted with RF;
• RF is halogen, OH, CN, NO2, SCN, SF5, C1-C6 alkyl, C1-C6 alkoxy, C2-C6-alkenyl, C2-C6 alkynyl, C1-C6 alkoxy-C1-C4 alkyl, C1-C6 alkoxy-C1-C4 alkoxy, C3-C6 cycloalkyl, C3-C6-cycloalkoxy, C3-C6 cycloalkyl-C1-C4 alkyl, C3-C6-cycloalkoxy-C1-C4 alkyl, which groups are unsubstituted or substituted with halogen;
• R2 is H, halogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkoxy, C1-C6-sulfenyl, C1-C6-sulfinyl, or C1-C6-sulfonyl, which groups are unsubstituted or halogenated;
• phenyl or benzyl, wherein the rings are unsubstituted or substituted with RF;
• R3 is H, halogen;
• C1-C6-alkyl, C1-C6-alkoxy, C3-C6-cycloalkyl, which are unsubstituted or substituted with RF;
• or
• phenyl or benzyl, wherein the aromatic ring of the aforementioned groups may be unsubstituted or substituted with RF;
• G is phenyl or 6-membered hetaryl;
• R4 is H, halogen, C(CN)R41R42, C(R44)═N—OR43, C(R44)═N—N(R45R46) C(O)R44, N═S(O)(R41R42), N(R43)C(O)R44, N(R43)C(═N—OR43)R44;
• OC(CN)R41R42, C1-C6-alkyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, or six-membered hetaryl, which groups are unsubstituted or substituted with RG;
• RGH, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, N(R12R13), S(O)m—C1-C4-haloalkyl, C1-C4-alkylcarbonyl, or C1-C4-haloalkylcarbonyl;
• or two groups RG bonded to two adjacent atoms form a 4- to 6-membered carbo- or heterocyclic ring which is unsubstituted or partially or fully substituted with RF;
• R41, R42 are independently H, halogen, CN, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, S(O)m—C1-C4-alkyl, C1-C4-alkyl-S(O)m—C1-C4-alkyl, or C1-C4-alkoxycarbonyl;
• R41 and R42 may also form together with the carbon atom to which they are bound, a C3-C6-cycloalkyl which is unsubstituted or substituted with halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• R43 is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy-C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6-cycloalkoxy-C1-C4-alkyl, which groups are unsubstituted or substituted with halogen and/or CN;
• phenyl or benzyl, which groups are unsubstituted or substituted with RF;
• R44 is H, CN, OH, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy-C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6-cycloalkoxy-C1-C4-alkyl, which groups are unsubstituted or substituted with halogen;
• phenyl or benzyl, which groups are unsubstituted or substituted with RF;
• R45, R46 are independently H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy-C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, C3-C6-cycloalkoxy-C1-C4-alkyl, C1-C6-alkyl-carbonyl, C1-C6-alkoxy-carbonyl, which groups are unsubstituted or substituted with halogen;
• phenyl or benzyl, which groups are unsubstituted or substituted with RF;
• NR45R46 may also form an N-bound, saturated 5- to 8-membered heterocycle, which additionally to the nitrogen may have 1 or 2 further heteroatoms selected from O, S(O)m, and N—R′, wherein R′ is H or C1-C6-alkyl, and which heterocycle is unsubstituted or substituted with halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• A is CH, CRA, or N;
• RA is halogen, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C6-haloalkyl, C1-C6-halocycloalkyl, OR43, S(O)m—R43;
• wherein rings are unsubstituted or substituted with R42;
• m is 0, 1, or 2;
• n is 0, 1, or 2;
• Y is O or NRY;
• RY is H or C1-C4-alkyl;
• R5 is C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl;
• and N-oxides, tautomers, stereoisomers, and agriculturally or veterinarily acceptable salts thereof.