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US 2025/0026656 A1Published application
Continuous cleaning system for halogen salts
AssigneeDeutsches Zentrum für Luft- und Raumfahrt e.V.
InventorsWenjin DING, Qing GONG, Thomas BAUER
Life of this patent
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Abstract
Processes and devices for reducing impurities in halogen salts, where the halogen salt is brought into contact with an active metal. The halogen salts purified in this way are suitable for use as high-temperature storage materials in thermal power plants and for industrial process heat, or as electrolytes in batteries.
Claims16
A process for reducing impurities in a halogen salt or halogen salt mixtures of two, three or more halogen salts, comprising the following steps:
- a) providing a container in which the halogen salt or halogen salt mixture is brought into contact with an active metal,
- b) providing said halogen salt or halogen salt mixture, which is in a liquid form,
- c) providing an active metal,
- d) contacting said halogen salt or halogen salt mixture with said active metal in an inert atmosphere at a temperature that is above the melting temperature of said active metal and above the melting temperature of said halogen salt/halogen salt mixture, whereby impurities in said halogen salt or halogen salt mixture react with said active metal, to obtain a halogen salt or halogen salt mixture having a proportion of impurities of 0.05% by weight or less, especially of 0.01% by weight or less, and
- e) separating the purified halogen salt or halogen salt mixture,
- wherein
- said halogen salt is a halogen salt of an alkali metal, or an alkaline earth metal, or a transition metal, or a metal of group 13 or 14 of the periodic table,
- said inert atmosphere consists of nitrogen and/or noble gas, and
- said active metal is selected to
- be immiscible with the molten halogen salts,
- have an electromotive force (EMF) that is not larger than that of the metals forming the cations of the halogen salt or salts,
- have an electromotive force (EMF) that is larger than that of the corrosive impurities of the halogen salt or salts, and
- have a density different from that of the purified halogen salt.
10 more elements
Dependencies are inferred from the claim text.