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AssigneesChina Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology, Sinopec
InventorsDawei LAN, Weimin YANG, Zhendong WANG, Xiangcheng LI, Chuang LIU, Junjie LI, Wennian WANG
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A hydrogenation-acid catalysis bifunctional catalyst, based on the mass of the catalyst, contains 80-99.8% of a silica-alumina molecular sieve component, 0.2-2% of a metal component with hydrogenation activity supported on the molecular sieve, and 0-20% of a hydrocarbyl modifying component. The hydrogenation active metal is selected from ruthenium, platinum, palladium, copper, nickel, or a combination thereof. The hydrocarbyl modifying component is a C1-20 hydrocarbyl. The catalyst has dual functions of hydrogenation and acid catalysis, and is suitable for benzene hydroalkylation reaction and alkane hydroisomerization reaction. It can be used in the benzene hydroalkylation to produce cyclohexylbenzene with high benzene conversion rate, high product selectivity, and less by-product cyclohexane.
A hydrogenation-acid catalysis bifunctional catalyst, based on the mass of the catalyst, containing 80-99.8% of a silica-alumina molecular sieve component, 0.2-2% of a metal component with hydrogenation activity supported on the molecular sieve, and 0-20% of a hydrocarbyl modifying component, wherein the hydrogenation active metal is selected from ruthenium, platinum, palladium, copper, nickel, or a combination thereof, more preferably selected from ruthenium, palladium, or a combination thereof, the hydrocarbyl modifying component is a C1-20 hydrocarbyl, preferably a C1-10 hydrocarbyl, more preferably selected from methyl, ethyl, propyl, isopropyl, butyl, phenyl, benzyl, phenethyl, or a combination thereof.
Dependencies are inferred from the claim text.