Back to results
US 2024/0407251 A1Published application
Light emitting element, polycyclic compound for the same, and display device including the same
AssigneeSamsung Display Co., Ltd.
InventorsChanseok OH, Sun Young PAK, MinJae SUNG, Mun-Ki SIM, Minjung JUNG, Seonhyoung HUR
Life of this patent
Estimating the term…
Abstract
A light emitting element including a first electrode, a second electrode provided on the first electrode, and an emission layer provided between the first electrode and the second electrode is provided. The emission layer includes a first compound and may exhibit high efficiency and long service life characteristics.
Claims24
A light emitting element comprising:
- a first electrode;
- a second electrode on the first electrode;
- and
- an emission layer between the first electrode and the second electrode,
- wherein the emission layer comprises:
- a first compound represented by Formula 1;
- and
- at least one of a second compound represented by Formula HT-1 or a third compound represented by Formula ET-1:
- wherein, in Formula 1,
- X is NRa, CRbRc, SiRdRe, O, or S,
- R1 and R2 are each independently represented by Formula 2,
- R3 to R6 are each independently a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms,
- Ra to Re are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms,
- a and b are each independently an integer of 1 to 4,
- c is an integer of 0 to 3, and
- d is an integer of 0 to 4, and
- wherein, in Formula 2,
- Rs is a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- e is an integer of 1 to 5:
- wherein, in Formula HT-1,
- A1 to A8 are each independently N or CR51,
- L1 is a direct linkage, a substituted or unsubstituted arylene group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring-forming carbon atoms,
- Ya is a direct linkage, CR52R53, or SiR54R55,
- Ar1 is a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- R51 to R55 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted silyl group, a substituted or unsubstituted thio group, a substituted or unsubstituted oxy group, a substituted or unsubstituted amine group, a substituted or unsubstituted boron group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms, and/or are bonded to an adjacent group to form a ring,
- and
- wherein, in Formula ET-1,
- at least one among X1 to X3 is N, and each of the remaining X1 to X3 is CR56,
- R56 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms,
- b1 to b3 are each independently an integer of 0 to 10,
- Ar2 to Ar4 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- L2 to L4 are each independently a direct linkage, a substituted or unsubstituted arylene group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring-forming carbon atoms.
29 more elements
A polycyclic compound represented by Formula 1:
- wherein, in Formula 1,
- X is NRa, CRbRc, SiRdRe, O, or S,
- R1 and R2 are each independently represented by Formula 2,
- R3 to R6 are each independently a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms,
- Ra to Re are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms,
- a and b are each independently an integer of 1 to 4,
- c is an integer of 0 to 3, and
- d is an integer of 0 to 4,
- and
- wherein, in Formula 2,
- Rs is a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- e is an integer of 1 to 5.
9 more elements
A display device comprising:
- a base layer;
- a circuit layer on the base layer;
- and
- a display element layer which is on the circuit layer and comprises a light emitting element,
- wherein the light emitting element comprises a first electrode, a second electrode on the first electrode, and an emission layer between the first electrode and the second electrode,
- wherein the emission layer comprises:
- a first compound represented by Formula 1;
- and
- at least one of a second compound represented by Formula HT-1 or a third compound represented by Formula ET-1:
- wherein, in Formula 1,
- X is NRa, CRbRc, SiRdRe, O, or S,
- R1 and R2 are each independently represented by Formula 2,
- R3 to R6 are each independently a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms,
- Ra to Re are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms,
- a and b are each independently an integer of 1 to 4,
- c is an integer of 0 to 3, and
- d is an integer of 0 to 4,
- wherein, in Formula 2,
- Rs is a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- e is an integer of 1 to 5:
- wherein, in Formula HT-1,
- A1 to A8 are each independently N or CR51,
- L1 is a direct linkage, a substituted or unsubstituted arylene group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring-forming carbon atoms,
- Ya is a direct linkage, CR52R53, or SiR54R55,
- Ar1 is a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- R51 to R55 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted silyl group, a substituted or unsubstituted thio group, a substituted or unsubstituted oxy group, a substituted or unsubstituted amine group, a substituted or unsubstituted boron group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 60 ring-forming carbon atoms, and/or are bonded to an adjacent group to form a ring,
- and
- wherein, in Formula ET-1,
- at least one among X1 to X3 is N, and each of the remaining X1 to X3 is CR56,
- R56 is a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 60 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group of 2 to 60 ring-forming carbon atoms,
- b1 to b3 are each independently an integer of 0 to 10,
- Ar2 to Ar4 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring-forming carbon atoms, and
- L2 to L4 are each independently a direct linkage, a substituted or unsubstituted arylene group having 6 to 30 ring-forming carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring-forming carbon atoms.
30 more elements
Dependencies are inferred from the claim text.