A membrane (m) comprising a sulfonated poly(arylene ether sulfone) polymer (sp) and a non-sulfonated poly(arylene sulfone) polymer (p)
AssigneeBASF SE
InventorsOliver GRONWALD, Martin WEBER, Christian MALETZKO
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Abstract
The present invention relates to a membrane (M) comprising a sulfonated poly(arylene ether sulfone) polymer (sP) and a non-sulfonated poly(arylene sulfone) polymer (P), to a method for the preparation of the membrane (M) and to the use of the membrane as nanofiltration membrane. Further, the present invention relates to a monolithic film (F) comprising a sulfonated poly(arylene ether sulfone) polymer (sP) and a non-sulfonated poly(arylene sulfone) polymer (P), wherein the monolithic film has a contact angle of 63 to 77°.
Claims12
-14. (canceled)
A membrane comprising a blend of
- (A) a sulfonated poly(arylene ether sulfone) polymer and
- (B) a non-sulfonated poly(arylene sulfone) polymer, wherein the membrane has a minimal pore diameter of <5 nm and a pure water permeation of >50 kg/(h m2 bar) and wherein the membrane is a nanofiltration membrane, wherein the average pore diameter is determined by gas adsorption-desorption experiments with nitrogen and Harkins-Jura analysis and rejection of diluted poly(ethylene oxide) solutions with a molecular weight of 8 000 g/mol or diluted rose Bengal with a molecular weight of 1 017 g/mol, and the pure water permeation is determined using a pressure cell with a diameter of 74 mm using ultrapure water (salt-free water, filtered by a Millipore UF-system) at 23° C. and 1 bar water pressure, wherein
- the membrane comprises from 15 to 80% by weight of the sulfonated poly(arylene ether sulfone) polymer, based on the total weight of the membrane, and wherein
- the sulfonated poly(arylene ether sulfone) polymer comprises units of formula (III)
- and/or formula (IV)
A monolithic film comprising
- (A) a sulfonated poly(arylene ether sulfone) polymer and
- (B) a non-sulfonated poly(arylene sulfone) polymer,
- wherein the monolithic film has a contact angle of 63 to 77°, wherein the contact angle is determined by time-resolved automated image analysis at 23° C. placing 8 to 10 drops of deionized water on the sample, and wherein
- the monolithic film comprises from 15 to 80% by weight of component (A) and from 20 to 85% by weight of component (B), each based on the total weight of the monolithic film.
Dependencies are inferred from the claim text.