# US 2024/0367385 A1 · Method for digital analytic correction of photoresponsive material reactivity in additive manufacturing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2024/0367385 A1 - Document ID: US20240367385A1 - Status: Published application - Kind: A1 - Application number: 18/688,538 - Filed: 2022-08-30 - Published: 2024-11-07 - Earliest claimed: 2021-09-03 - Assignees: Readily3D SA - Applicants: Readily3D SA - Inventors: Paul DELROT; Damien LOTERIE - Web page: https://patentgrep.com/patent/US20240367385A1 ## CPC - B29C 64/393: for controlling or regulating additive manufacturing processes - B22F 10/28: Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] - B22F 10/36: of energy beam parameters - B22F 10/85: for controlling or regulating additive manufacturing processes - B28B 1/001: {Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material (selective deposition modelling of metallic powder B22F10/00; rapid manufacturing of 3D objects in general and in particular of plastics B29C64/00)} - B28B 17/0081: {Process control} - B29C 64/124: using layers of liquid which are selectively solidified - B29C 64/153: using layers of powder being selectively joined, e.g. by selective laser sintering or melting - B29C 64/255: Enclosures for the building material, e.g. powder containers - B29C 64/268: using laser beams; using electron beams [EB] - B29C 64/386: Data acquisition or data processing for additive manufacturing - B33Y 10/00: Processes of additive manufacturing - B33Y 30/00: Apparatus for additive manufacturing; Details thereof or accessories therefor - B33Y 50/00: Data acquisition or data processing for additive manufacturing - B33Y 50/02: for controlling or regulating additive manufacturing processes - B29K 2105/0032: {Pigments, colouring agents or opacifiyng agents} - B29K 2105/16: Fillers - B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00) - B22F: WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER (making alloys by powder metallurgy C22C); APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER - B28B: SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER (foundry moulding B22C; working stone or stone-like material B28D; shaping of substances in a plastic state, in general B29C; making layered products not composed wholly of these substances B32B) - B33Y: ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING - B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS ## Abstract The invention discloses a method and system to digitally compensate for reactivity inhomogeneities of a photoresponsive material within a build volume of an additive manufacturing system, which offers significant advantages for the production of high-fidelity and high-accuracy three-dimensional objects. The method comprises a) Providing a digital model of said three-dimensional object, b) defining a sequence of patterns of light (31) from said digital model, and c) irradiating with each of said patterns of light (31) according to the defined sequence a photoresponsive material (32) that is capable of alteration of its material phase upon irradiation by light, thereby creating a three-dimensional distribution of alterations within the photoresponsive material (32) which physically reproduces said three-dimensional object, thereby creating the three-dimensional object. The step of defining said sequence of patterns of light (31) involves a compensation of an expected light intensity of said patterns of light (31) for any deviations of an alteration rate in said photoresponsive material caused by auto-acceleration or auto-deceleration, so as to obtain a constant alteration rate throughout said photoresponsive material (32), wherein said compensation is computed from a predicted three-dimensional light dose distribution in the photoresponsive material (32) and a function describing an alteration response of the photoresponsive material (32) to light dose. ## Claims ### Claim 1 A method for producing a three-dimensional object, the method comprising: a) providing a digital model of said three-dimensional object, b) defining a sequence of patterns of light from said digital model, and c) irradiating with each of said patterns of light according to the defined sequence a photoresponsive material that is capable of alteration of its material phase upon irradiation by light, thereby creating a three-dimensional distribution of alterations within the photoresponsive material which physically reproduces said three-dimensional object, thereby creating the three-dimensional object, wherein the step of defining said sequence of patterns of light involves a compensation of an expected light intensity of said patterns of light for any deviations of an alteration rate in said photoresponsive material caused by auto-acceleration or auto-deceleration, so as to obtain a constant alteration rate throughout said photoresponsive material, wherein said compensation is computed from a predicted three-dimensional light dose distribution in the photoresponsive material and a function describing an alteration response of the photoresponsive material to light dose. ### Claim 2 (depends on 1) The method according to claim 1, wherein said computation of said compensation comprises a convolution or deconvolution of said predicted three-dimensional light dose distribution in the photoresponsive material with a function describing an elementary auto-acceleration or auto-deceleration alteration response of the photoresponsive material to an elementary light dose. ### Claim 3 (depends on 2) The method according to claim 2, wherein said function describing an elementary auto-acceleration or auto-deceleration alteration response of the photoresponsive material to an elementary light dose comprises an impulse response function, wherein said impulse response function comprises the influence of an effect selected from the group consisting of: heat generated within a specific area of said photoresponsive material, said heat influencing the reaction rate within said specific area; viscosity, photobleaching, scattering, and any combination thereof. ### Claim 4 (depends on 1) The method according to claim 1, wherein said predicted three-dimensional light dose distribution in the photoresponsive material is obtained by the following steps: defining a target alteration distribution in said photoresponsive material from said digital model of said three-dimensional object; defining an input alteration distribution in said photoresponsive material using said target alteration distribution; defining said sequence of patterns of light from said input alteration distribution in said photoresponsive material; and deriving from said sequence of patterns of light said predicted three-dimensional light dose distribution within said photoresponsive material. ### Claim 5 (depends on 2) The method according to claim 2, wherein said convolution of said predicted three-dimensional light dose distribution by said function provides a predicted three-dimensional alteration distribution within said photoresponsive material, which is used for correcting said input alteration distribution in said photoresponsive material such that the predicted alteration distribution more closely matches said target alteration distribution. ### Claim 6 (depends on 5) The method according to claim 5, wherein from said corrected input alteration distribution a compensated sequence of patterns of light is derived, which is used in step c) for creating the three-dimensional object. ### Claim 7 (depends on 1) The method according to claim 1, wherein said compensation is repeated until a predetermined threshold for a reduction of distortion of alteration between the predicted alteration distribution and the target alteration distribution has been reached. ### Claim 8 (depends on 2) The method according to claim 2, wherein said convolution is performed analytically, or in the Fourier domain, or algebraically, or point-by-point, or with a combination thereof. ### Claim 9 (depends on 2) The method according to claim 2, wherein said function describing an elementary auto-acceleration or auto-deceleration alteration response of the photoresponsive material to an elementary light dose comprises one or more scaling coefficients that affect the height, the width, or both the height and the width of said function. ### Claim 10 (depends on 9) The method according to claim 9, wherein said scaling coefficients are measured experimentally on a sample of said photoresponsive material. ### Claim 11 (depends on 1) The method according to claim 1, wherein said sequence of patterns of light is provided by computing a sequence of back-projections describing the three-dimensional object to be formed from different orientation angles of said object, or alternatively from different layers of said object. ### Claim 12 A system for producing a three-dimensional object from a photoresponsive material, the system comprising: a first projection unit capable of emitting controlled spatial patterns of light; a means for computing a sequence of projections describing the three-dimensional object to be formed along different orientation angles, different layers, or different combinations of orientation angles and layers of said object; said projections being used to define said controlled patterns of light, wherein said means is configured to provide a compensation of an expected light intensity of said projections for any deviations of an alteration rate in said photoresponsive material caused by auto-acceleration or auto-deceleration, so as to obtain a constant alteration rate throughout said photoresponsive material, wherein said compensation is computed from a predicted three-dimensional light dose distribution in the photoresponsive material and a function describing an alteration response of the photoresponsive material to light dose; a vessel, said vessel intended to contain a volume of photoresponsive material, and said vessel and the intended photoresponsive material defining a build volume; wherein the first projection unit is arranged in the system to irradiate said build volume with said controlled patterns of light; and a direction varying means, or a position varying means, or a means able to vary both position and direction, operatively associated with said first projection unit, for controllably varying a direction or position of incidence of said patterns of light relative to said build volume, either by rotating and/or moving the build volume within the field of illumination of the first projection unit, or by rotating and/or moving the first projection unit relative to the build volume, or a combination of both of these rotations and/or motions, and for executing the computed sequence of projections by irradiating the photoresponsive material with the controlled patterns of light from directions and positions corresponding to the different orientation angles and positions thereby creating a three-dimensional distribution of alterations of the photoresponsive material, and creating the three-dimensional object. ### Claim 13 (depends on 12) The system according to claim 12, wherein said computation of said compensation comprises a convolution or deconvolution of said predicted three-dimensional light dose distribution in the photoresponsive material with a function describing an elementary auto-acceleration or auto-deceleration alteration response of the photoresponsive material to an elementary light dose. ### Claim 14 (depends on 12) The system according to claim 12, wherein said system is a volumetric additive manufacturing system. ### Claim 15 (depends on 12) The system according to claim 12, wherein said vessel comprises at least an inlet and an outlet, said inlets and outlet being used for any post-processing steps from the group consisting of: developing said produced three-dimensional object, curing said produced three-dimensional object, and perfusing said produced three-dimensional object. ### Claim 16 (depends on 10) The method according to claim 10 wherein said scaling coefficients are derived using a machine learning process that is fed with said experimental measurements on said sample of said photoresponsive material. ### Claim 17 (depends on 12) The system according to claim 12 comprising a second projection unit which is capable of emitting controlled spatial patterns of light. ### Claim 18 (depends on 12) The system according to claim 12 wherein the vessel is optically transparent to said patterns of light. ### Claim 19 (depends on 14) The system according to claim 14 wherein the volumetric additive manufacturing system is selected from the group consisting of a tomography-based additive manufacturing system and a dual color-based additive manufacturing system. ### Claim 20 (depends on 15) The system according to claim 15 wherein the system comprises at least two inlets and at least two outlets.