Method for Producing Compound, Compound, and Metal Catalyst
AssigneeJapan Science and Technology Agency
InventorsTsuyoshi Mita, Satoshi Maeda, Hideaki Takano
Life of this patent
Estimating the term…
Abstract
One aspect of the present invention is a method for producing a compound represented by following general formula (1), the method being characterized by including a step of mixing ethylene, a compound represented by following general formula (2), and a compound represented by following general formula (3) to react with each other to give a compound represented by following general formula (4): A1 to A4 each independently represent an aromatic group, and Z1 and Z2 each independently represent an oxygen atom, a sulfur atom, or a borane (BH3), Z3 represents an oxygen atom or a sulfur atom, n1 to n3 each independently represent 0 or 1, and X represents a halogen atom.
Claims19
A method for producing a compound (1) represented by following general formula (1):
- wherein in the general formula (1), A1 to A4 each independently represent an aromatic group,
- Z1 and Z2 each independently represent an oxygen atom, a sulfur atom, or a borane (BH3),
- represents a bond between a phosphorus atom and Z1 or Z2, and
- n1 and n2 each independently represent 0 or 1,
- the method for producing being characterized by comprising a step of mixing ethylene, a compound (2) represented by following general formula (2), and a compound (3) represented by following general formula (3) to react with each other to give a compound (4) represented by following general formula (4):
- wherein in the general formulas (2) to (4), A1 to A4 have the same meanings as A1 to A4 in the general formula (1), respectively,
- Z3 represents an oxygen atom or a sulfur atom,
- n3 represents 0 or 1, and
- X represents a halogen atom.
A compound represented by following general formula (9):
- wherein in the general formula (9), A1 to A4 each independently represent an aromatic group, and
- any one of following requirements (a) to (c) is satisfied:
- Requirement (a):
- two types of aromatic groups each with a substituent are selected as A1 to A4, and A1 is an aromatic group different from A2, A3 is an aromatic group identical to A4, and the substituent is any one selected from the group consisting of a substituted hydrocarbon group, a halogen atom, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group;
- Requirement (b):
- at least three types of aromatic groups each with a substituent are selected as A1 to A4;
- and
- Requirement (c):
- A1 is an aromatic group identical to A2, and A3 is an aromatic group identical to A4, and when A1 and A2 are referred to as Group I, and A3 and A4 are referred to as Group II, Group I and Group II are aromatic groups different from each other, and any one of the following (i) to (iv) is satisfied:
- (i) each of Group I and Group II is an aromatic group with no substituent;
- (ii) one of Group I and Group II is an aromatic hydrocarbon group with no substituent and having at least 10 carbon atoms, or an aromatic heterocyclic compound residue, and the other of Group I and Group II is an aromatic group with a substituent;
- (iii) one of Group I and Group II is an aromatic group having an unsubstituted hydrocarbon group as a substituent, and the other of Group I and Group II is an aromatic group having any substituent that is selected from the group consisting of an unsubstituted hydrocarbon group, a halogen atom, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group;
- and
- (iv) each of Group I and Group II is an aromatic group having any substituent that is selected from the group consisting of a substituted hydrocarbon group, a halogen atom, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group.
A compound represented by following general formula (10):
- wherein in the general formula (10), A1 to A4 each independently represent an aromatic group,
- Z1 and Z2 each independently represent an oxygen atom, a sulfur atom, or a borane (BH3),
- n1 and n2 each independently represent 0 or 1, and n1=n2=0 does not hold, and
- any one of following requirements (a) to (c) is satisfied:
- Requirement (a):
- two types of aromatic groups each with a substituent are selected as A1 to A4, and A1 is an aromatic group different from A2, A3 is an aromatic group identical to A4, and the substituent is any one selected from the group consisting of a substituted hydrocarbon group, a halogen atom, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group;
- Requirement (b):
- at least three types of aromatic groups each with a substituent are selected as A1 to A4;
- and
- Requirement (c):
- A1 is an aromatic group identical to A2, and A3 is an aromatic group identical to A4, when A1 and A2 are referred to as Group I, and A3 and A4 are referred to as Group II, Group I and Group II are aromatic groups different from each other, and any one of the following (i) to (iv) is satisfied:
- (i) each of Group I and Group II is an aromatic groups with no substituent;
- (ii) one of Group I and Group II is an aromatic hydrocarbon group with no substituent and having at least 10 carbon atoms, or an aromatic heterocyclic compound residue, and the other of Group I and Group II is an aromatic group with a substituent;
- (iii) one of Group I and Group II is an aromatic group having an unsubstituted hydrocarbon group as a substituent, and the other of Group I and Group II is an aromatic group having any substituent that is selected from the group consisting of an unsubstituted hydrocarbon group, a halogen atom, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group;
- and
- (iv) each of Group I and Group II is an aromatic group having any substituent that is selected from the group consisting of a substituted hydrocarbon group, a halogen atom, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group.
Dependencies are inferred from the claim text.