Method for lactide and lactic acid recovery at polylactide (pla) production steps
AssigneeFuterro S.A.
InventorsPhilippe COSZACH, Martin VAN GANSBERGHE
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Abstract
An improved method is described for producing polylactide (PLA) whereby various gas streams containing lactide, lactic acid and water are recovered, are sent onto an assembly of packed columns for condensation, are brought into contact with a fluid at least comprising water, lactic acid and dissolved lactide; the fluid leaving the assembly of packed columns is recovered and is or is not filtered, the aqueous solution obtained via at least one exchanger is heated and sent into a feed tank under agitation which is continuously fed with a lactic acid solution, and hydrolysis of the lactide contained in the aqueous solution is performed in this feed tank.
Claims11
A Polylactide (PLA) preparation method with improved overall yield, of the method comprising:
- providing together or separately, various a plurality of gas streams containing lactide, lactic acid, and water;
- sending each of the plurality of gas streams onto an assembly of packed columns comprising at least one column, in which the gas stream will be condensed;
- bringing the gas stream, in the assembly of packed columns, in contact with a wetting fluid at a temperature of 1° C. to 30° C., this fluid comprising water, lactic acid and dissolved lactide;
- recovering the fluid leaving the assembly of packed columns at a temperature of 15° C. to 70° C., this fluid inter alia containing lactide in solid form of 0.1% to 20% by weight relative to a total weight of lactates contained in solution;
- optionally, filtering and extracting at least partially the precipitated lactide contained in this fluid;
- heating this aqueous solution, from which solid lactide may have been partially removed, via at least one exchanger, to bring the temperature to a value comprised between 50° C. and 95° C.;
- sending this acid aqueous solution into a feed tank under agitation and continuously fed with a stream of lactic acid, this feed tank being positioned upstream of the present treatment circuit and being held at a temperature of 50° C. to 95° C.;
- and
- in this feed tank, converting the lactide contained in the aqueous solution to lactic acid and/or lactic acid oligomer by performing hydrolysis.
Dependencies are inferred from the claim text.