Acetal modifier, polymer, chemically amplified positive resist composition, and resist pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsMasahiro Fukushima, Satoshi Watanabe, Kenji Funatsu, Keiichi Masunaga, Masaaki Kotake, Yuta Matsuzawa
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Abstract
An acetal modifier affording a triple bond-bearing group serving as a protective group for an aliphatic or aromatic hydroxy group is provided as well as a polymer adapted to turn alkali soluble as a result of deprotection under the action of acid, the polymer comprising repeat units A1 having on side chain a structure including an aromatic hydroxy group protected with a triple bond-bearing group acid labile group. A chemically amplified positive resist composition comprising the polymer is also provided.
Claims16
An acetal modifier providing a triple bond-bearing group serving as a protective group for an aliphatic or aromatic hydroxy group.
A polymer adapted to turn alkali soluble as a result of deprotection under the action of acid, the polymer comprising repeat units A1 having on side chain a structure including an aromatic hydroxy group protected with an acid labile group having the formula (AL-1) or (AL-2):
- wherein RL1, RL2, RL6, RL7 and RL8 are each independently hydrogen or a C1-C15 hydrocarbyl group, RL1 and RL2 may bond together to form a ring with the carbon atom to which they are attached, and any two of RL6 to RL8 may bond together to form a ring with the carbon atom to which they are attached,
- RL3, RL1, RL9 and RL10 are each independently hydrogen or a C1-C20 hydrocarbyl group which may contain a heteroatom, RL3 and RM may bond together to form a ring with the carbon atom to which they are attached, and RL9 and RL10 may bond together to form a ring with the carbon atom to which they are attached,
- RL5 and RL11 are each independently hydrogen or a C1-C15 hydrocarbyl group,
- m1 and m2 are each independently an integer of 1 to 3, and
- the broken line designates a point of attachment to the oxygen atom of the aromatic hydroxy group.
Dependencies are inferred from the claim text.