Porous ceramic supports, membranes, methods and uses thereof
AssigneeNational University of Singapore
InventorsJohn Wang, Qilin Gu, How Yong Ng, Tze Chiang Albert Ng
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Abstract
This disclosure concerns methods of fabricating porous ceramic supports and supported ceramic membranes, comprising mixing a ceramic powder, a clay powder and a binder to form a mixture, kneading the mixture in an aqueous or non-aqueous medium and a humectant to form a ceramic paste, and aging the ceramic paste for at least 24 h. The ceramic powder is about 70 wt % to about 80 wt % in the ceramic paste. The clay powder is about 5 wt % to about 15 wt % in the ceramic paste. The ceramic powder has an average particle size of about 5 μm to about 20 μm. This disclosure also concerns porous ceramic supports and supported ceramic membranes thereof.
Claims21
1-39. (canceled)
A method of fabricating a ceramic paste, a porous ceramic support or a supported ceramic membrane, comprising:
- a) mixing a ceramic powder, a clay powder and a binder to form a mixture;
- b) kneading the mixture of step (a) in an aqueous or non-aqueous medium and a humectant to form a ceramic paste;
- and
- c) aging the ceramic paste for at least 24 h;
- wherein the ceramic powder is about 70 wt % to about 80 wt % in the ceramic paste;
- wherein the clay powder is about 5 wt % to about 15 wt % in the ceramic paste;
- and
- wherein the ceramic powder has an average particle size of about 5 μm to about 20 μm.
A ceramic paste, comprising:
- a) a ceramic powder at about 70 wt % to about 80 wt % in the ceramic paste;
- b) a clay powder at about 5 wt % to about 15 wt % in the ceramic paste;
- c) a binder at about 2 wt % to about 8 wt % in the ceramic paste;
- d) a humectant at about 0.1 wt % to about 1.5 wt % in the ceramic paste;
- and
- e) an aqueous medium;
- wherein the ceramic powder has an average particle size of about 5 μm to about 20 μm;
- wherein the ceramic paste has a viscosity of about 1×104 Pa·s to about 5×10+Pa·s at a shear rate of about 10−1 s−1;
- and
- wherein the ceramic paste has a yield flow pressure of about 1000 Pa to about 1500 Pa.
A ceramic support, comprising:
- a) a ceramic at about 85 wt % to about 95 wt % in the ceramic support;
- and
- b) a clay at about 5 wt % to about 15 wt % in the ceramic support;
- wherein the ceramic has an average particle size of about 5 μm to about 20 μm;
- and
- wherein the ceramic support comprises an asymmetric porous structure having an inner body conterminous to an outer surface;
- wherein the inner body further comprises a plurality of voids;
- wherein the ceramic support has a porosity level of about 30% to about 50%.
Dependencies are inferred from the claim text.