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US 2024/0287223 A1Published application
Ligand Compound, Organochromium Compound and Catalyst Composition Comprising the Same
AssigneeLG Chem, Ltd.
InventorsSeok Pil Sa, Seok Sun Kim, Tae Hee Kim, Seung Hwan Jung, Eun Ji Shin, Yeon Ho Cho, Won Taeck Lim, Hee Jeong Kim
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Abstract
A ligand compound represented by the following Formula 1, which shows high catalyst activity and high selectivity to 1-hexene and 1-octene, and may perform ethylene oligomerization with excellent efficiency, an organochromium compound, a catalyst composition comprising the organochromium compound and a method for oligomerizing ethylene using the same, are described: wherein all the variables are described herein.
Claims15
A ligand compound represented by Formula 1:
- in Formula 1,
- R1 to R4 are each independently a trialkylsilyl group, where the alkyl group is an alkyl group of 1 to 4 carbon atoms, and
- R5 is a substituent represented by any one of Formulae 2 to 4:
- in Formulae 2 to 4,
- X1 to X6 are each independently —(CR6R7)n—, —O— or —S—, where X1 to X5 are not —O— or —S— simultaneously, and n is an integer selected from 0 to 3,
- R6 and R7 are each independently hydrogen, an alkyl group of 1 to 5 carbon atoms, a trifluoroalkyl group of 1 to 5 carbon atoms, an aryl group of 6 to 10 carbon atoms, or —NR8R9,
- R8 and R9 are each independently hydrogen or an alkyl group of 1 to 5 carbon atoms, and
- * is a part bonded to N of Formula 1.
5 more elements
Dependencies are inferred from the claim text.