Functional copolymer of a 1,3-diene and ethylene or a 1,3-diene, ethylene and an alpha-monoolefin
AssigneeCompagnie Generale Des Etablissements Michelin
InventorsFrançois JEAN-BAPTISTE-DIT-DOMINIQUE, Robert NGO, Julien THUILLIEZ
Life of this patent
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Abstract
A copolymer of a 1,3-diene and of an olefin is provided. The copolymer bears, at one of its chain ends, a functional group of formula —CH2—CH(CH3)—COOZ, Z being a hydrogen atom or a carbon-comprising group. A process of preparation of the copolymer is also provided. The olefin is ethylene or a mixture of ethylene and of an α-monoolefin.
Claims15
A process for the preparation of a copolymer of a 1,3-diene and of an olefin, the copolymer bearing, at one of its chain ends, a functional group of formula —CH2—CH(CH3)—COOZ, Z being a hydrogen atom or a carbon-comprising group, which process comprises the successive stages a), b) and c) and, optionally, a stage d),
- stage a) being the polymerization of a monomer mixture containing a 1,3-diene and an olefin in the presence of a catalytic system based at least on a metallocene of formula (Ia) and on an organomagnesium compound
- Cp1 and Cp2, which are identical or different, being chosen from the group consisting of fluorenyl groups, cyclopentadienyl groups and indenyl groups, the groups being substituted or unsubstituted,
- P being a group bridging the two groups Cp1 and Cp2 and comprising a silicon or carbon atom,
- Nd denoting a neodymium atom,
- L representing an alkali metal selected from the group consisting of lithium, sodium and potassium,
- N representing a molecule of an ether,
- x, which is or is not an integer, being equal to or greater than 0,
- y, which is an integer, being equal to or greater than 0,
- the olefin being ethylene or a mixture of ethylene and of an α-monoolefin,
- stage b) being the reaction of a methacrylate with the reaction product of the polymerization of stage a),
- stage c) being a chain termination reaction, and
- stage d) being a hydrolysis reaction.
A copolymer of a 1,3-diene and of an olefin, which copolymer bears, at one of its chain ends, a functional group of formula —CH2—CH(CH3)—COOZ, Z being a hydrogen atom or a carbon-comprising group, the olefin being ethylene or a mixture of ethylene and of an α-monoolefin.
Dependencies are inferred from the claim text.