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US 2024/0209252 A1Published application
Methods for stabilizing water sensitive clays and migrating fines in subterranean formations
AssigneesPfp Technology, LLC, Ascend Performance Materials Operations LLC
InventorsAziz Hikem, Madhukar Chetty, Derek Vaughn, Prasad Taranekar, Jeffery W. Balko
Life of this patent
Estimating the term…
Abstract
Clay stabilization compositions include one or a plurality of triamino compounds and/or derivatives thereof, fluids containing an effective amount of the clay stabilization compositions and methods for making and using same.
Claims20
A method comprising:
- drilling a well with a drilling fluid composition comprising:
- a base fluid;
- and
- an effective of a clay stabilizing composition comprising:
- one or more tri-functional primary amine compounds comprising one or more compounds of Formula I:
- and
- one or more salts comprising one or more compounds of Formula II:
- wherein:
- the R, R′, and R″ groups comprising the same or different hydrocarbyl linking groups including between 1 and 8 carbon atoms, and when the R, R′, and R″ groups including between 2 and 8 carbon atoms, then one or more carbon atoms may be replaced by acetate groups, or carbonyl groups,
- the R1-6 groups comprising the same or different hydrogen atoms or hydrocarbyl groups including between 1 and 6 carbon atoms, and when the R1-6 groups including between 2 and 6 carbon atoms, then one or more carbon atoms may be replaced by oxygen atoms, acetate groups, or carbonyl groups,
- the R7-9 groups are (a) absent and their associated nitrogen atoms do not bear a charge, (b) the same or different comprising a hydrogen atom and their associated nitrogen atoms bear a charge, or (c) the same or different comprising a hydrocarbyl group including between 1 and 24 carbon atoms and their associated nitrogen atoms bear a charge;
- provided that at least one of the R7-9 groups comprising a hydrogen atom or a hydrocarbyl group, and when the R7-9 groups including between 2 and 24 carbon atoms, then one or more carbon atoms may be replaced by oxygen atoms, acetate groups, or carbonyl groups;
- the X groups are the same or different counterions derived from an organic acid, an alkylating agent, a quaternizing agent, or mixtures thereof;
- n is an integer having a value of 1, 2 or 3;
- provided that each of the compounds of Formula (II) is neutral;
- the clay stabilizing composition stabilizes clay, reduces clay swelling, and reduces fines migration during drilling.
13 more elements
A method comprising:
- drilling a well with a stimulating fluid composition comprising:
- a base fluid;
- and
- an effective of a clay stabilizing composition comprising:
- one or more tri-functional primary amine compounds comprising one or more compounds of Formula I:
- and
- one or more salts comprising one or more compounds of Formula II:
- wherein:
- the R, R′, and R″ groups comprising the same or different hydrocarbyl linking groups including between 1 and 8 carbon atoms, and when the R, R′, and R″ groups including between 2 and 8 carbon atoms, then one or more carbon atoms may be replaced by acetate groups, or carbonyl groups,
- the R1-6 groups comprising the same or different hydrogen atoms or hydrocarbyl groups including between 1 and 6 carbon atoms, and when the R1-6 groups including between 2 and 6 carbon atoms, then one or more carbon atoms may be replaced by oxygen atoms, acetate groups, or carbonyl groups,
- the R7-9 groups are (a) absent and their associated nitrogen atoms do not bear a charge, (b) the same or different comprising a hydrogen atom and their associated nitrogen atoms bear a charge, or (c) the same or different comprising a hydrocarbyl group including between 1 and 24 carbon atoms and their associated nitrogen atoms bear a charge;
- provided that at least one of the R7-9 groups comprising a hydrogen atom or a hydrocarbyl group, and when the R7-9 groups including between 2 and 24 carbon atoms, then one or more carbon atoms may be replaced by oxygen atoms, acetate groups, or carbonyl groups;
- the X groups are the same or different counterions derived from an organic acid, an alkylating agent, a quaternizing agent, or mixtures thereof;
- n is an integer having a value of 1, 2 or 3;
- provided that each of the compounds of Formula (II) is neutral;
- the clay stabilizing composition stabilizes clay, reduces clay swelling, and reduces fines migration during drilling.
13 more elements
Dependencies are inferred from the claim text.