# US 2024/0201427 A1 · Multilayer Optical Film

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- Number: US 2024/0201427 A1
- Document ID: US20240201427A1
- Status: Published application
- Kind: A1
- Application number: 18/555,741
- Filed: 2022-04-05
- Published: 2024-06-20
- Earliest claimed: 2021-05-07
- Assignees: 3M Innovative Properties Company
- Applicants: 3M Innovative Properties Company
- Inventors: Lin Zhao; Gilles J. Benoit; Stephen A. Johnson
- Web page: https://patentgrep.com/patent/US20240201427A1

## CPC

- G02B 5/26: Reflecting filters (G02B5/28 takes precedence)
- G02B 5/287: {comprising at least one layer of organic material}
- G02B 5/3041: {comprising multiple thin layers, e.g. multilayer stacks}
- G02B 5/305: {including organic materials, e.g. polymeric layers}
- G02B 5/3083: {Birefringent or phase retarding elements (G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001)}
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS

## Abstract

A multilayer optical film includes a plurality of polymeric first layers numbering at least 10 in total where each of the first layers has an average thickness less than about 500 nm. For a p-polarized incident light, and for each of a first incident angle and a second incident angle greater than the first incident angle by at least about 40 degrees: a reflectance of each of the optical film and the plurality of polymeric first layers versus wavelength has a reflection band having a left band edge (LBE) at a short wavelength side of the reflection band and a right band edge (RBE) at a long wavelength side of the reflection band. A separation between the RBEs is less than a separation between the LBEs for the first incident angle, and a separation between the RBEs is greater than a separation between the LBEs for the second incident angle.

## Claims

### Claim 1

A multilayer optical film comprising a plurality of polymeric first layers numbering at least 10 in total disposed on a plurality of polymeric second layers numbering at least 10 in total, each of the first and second layers having an average thickness of less than about 500 nm, such that in a predetermined wavelength range that is at least about 200 nm wide and is disposed between about 200 nm and about 2000 nm, for a p-polarized incident light, and for each of a first incident angle and a second incident angle greater than the first incident angle by at least about 40 degrees:
an optical reflectance of each of the optical film and the plurality of polymeric first layers versus wavelength comprises a reflection band comprising a left band edge (LBE) at a short wavelength side of the reflection band where the reflectance generally increases with increasing wavelength, and a right band edge (RBE) at a long wavelength side of the reflection band where the reflectance generally decreases with increasing wavelength, such that a separation between the RBEs of the optical film and the first layers is less than a separation between the LBEs of the optical film and the first layers for the first incident angle, and a separation between the RBEs of the optical film and the first layers is greater than a separation between the LBEs of the optical film and the first layers for the second incident angle.

### Claim 2 (depends on 1)

The multilayer optical film of claim 1, wherein the plurality of polymeric second layers comprises a plurality of alternating first and second optical layers comprising respective refractive indices nx1 and nx2 along a same in-plane x-direction, respective refractive indices ny1 and ny2 along an in-plane y-direction orthogonal to the x-direction, and respective refractive indices nz1 and nz2 along a thickness direction of the polymeric second layers orthogonal to the x- and y-directions, wherein for at least one wavelength in the predetermined wavelength range:
each of |nx1−nx2| and |ny1−ny2| is less than about 0.02; and
nz1−nz2 is greater than about 0.03.

### Claim 3 (depends on 1)

The multilayer optical film of claim 1 further comprising a plurality of polymeric third layers numbering at least 10 in total, each of the third layers having an average thickness of less than about 500 nm, the plurality of polymeric third layers comprising a plurality of alternating third and fourth optical layers comprising respective refractive indices nx3 and nx4 along a same in-plane x-direction, respective refractive indices ny3 and ny4 along an in-plane y-direction orthogonal to the x-direction, and respective refractive indices nz3 and nz4 along a thickness direction of the polymeric third layers orthogonal to the x- and y-directions, wherein for at least one wavelength in the predetermined wavelength range, nz4−nz3≥nx4−nx3≥0.02.

### Claim 4 (depends on 1)

The multilayer optical film of claim 1, wherein for the p-polarized incident light and the first incident angle, an optical reflectance versus wavelength of the plurality of polymeric second layers does not comprise a reflection band in the predetermined wavelength range.

### Claim 5 (depends on 1)

The multilayer optical film of claim 1, wherein in the predetermined wavelength range and for the p-polarized incident light:
for the first incident angle, the optical film has a peak optical reflectance of greater than about 50%, and the plurality of polymeric second layers has a substantially constant optical reflectance having a standard deviation of less than about 3%; and
for the second incident angle, the optical film and the plurality of polymeric second layers each has a peak optical reflectance of greater than about 40%.

### Claim 6 (depends on 1)

The multilayer optical film of claim 1, wherein the reflection band for each of the optical film and the plurality of polymeric first layers comprises a full width at half maximum (FWHM), such that for the first incident angle, at least one of the two FWHMs overlaps at least 50% of the other one of the two FWHMs, and for the second incident angle, wavelengths at the half maximum reflectances along the RBEs of the optical film and the first layers shift to smaller wavelengths by CS and MS, respectively, CS being less than MS by at least about 10 nm.

### Claim 7

A multilayer optical film comprising a plurality of polymeric first layers numbering at least 10 in total disposed on a plurality of polymeric second layers number at least 10 in total, each of the first and second layers having an average thickness of less than about 500 nm, such that in a predetermined wavelength range that is at least about 200 nm wide and is disposed between about 200 nm and about 2000 nm, and for a p-polarized incident light, maximum reflectances of the optical film and the plurality of polymeric first layers are respectively Cmax and Lmax for a first incident angle and C′max and L′max for a second incident angle greater than the first incident angle by at least about 40 degrees, wherein Cmax and Lmax are within 20% of each other, and C′max≥2 L′max.

### Claim 8 (depends on 7)

The multilayer optical film of claim 7, wherein for the p-polarized incident light and the first incident angle, optical reflectances of the optical film and the plurality of polymeric first layers versus wavelength comprise respective first and second reflection bands comprising respective full width at half maxima FW1 and FW2, and wherein increasing an incident angle of the p-polarized incident light from the first incident angle to the second incident angle, shifts the first and second reflection bands to respective third and fourth reflection bands at smaller wavelengths with respective full width at half maxima FW′1 and FW′2, FW′1 being less than FW1 by less than about 30%, FW′2 being less than FW2 by more than about 35%.

### Claim 9

A multilayer optical film comprising a plurality of alternating first and second polymeric layers disposed on, and integrally formed with, a plurality of alternating third and fourth polymeric layers and a plurality of alternating fifth and sixth polymeric layers, each of the three pluralities comprising at least 20 polymeric layers in total, each of the first through sixth polymeric layers having an average thickness of less than about 500 nm, the first through sixth polymeric layers comprising respective refractive indices nx1 through nx6 along a same in-plane x-direction, respective refractive indices ny1 through ny6 along an in-plane y-direction orthogonal to the x-direction, and respective refractive indices nz1 through nz6 along a thickness direction of the polymeric layers orthogonal to the x- and y-directions, such that for at least one wavelength in a visible wavelength range extending from about 420 nm to about 680 nm;
each of nx1 and ny1 is greater than nz1 by at least 0.02;
a magnitude of a maximum difference between nx3, ny3 and nz3 is less than 0.02; and
each of nx5 and ny5 is less than nz5 by at least 0.02.

### Claim 10

A multilayer optical film comprising a plurality of polymeric first layers disposed on, and integrally formed with, a plurality of polymeric second layers, each of the two pluralities comprising at least 10 polymeric layers in total, each of the first and second layers having an average thickness of less than about 500 nm, such that for a p-polarized incident light in a predetermined wavelength range that is at least about 200 nm wide and is disposed between about 200 nm and about 2000 nm;
for a first incident angle, an optical reflectance of the plurality of polymeric first layers, but not the plurality of polymeric second layers, versus wavelength comprises a reflection band, the reflection band having a full width at half maximum (FWHM) of greater than about 10 nm; and
for a second incident angle greater than the first incident angle by at least about 40 degrees, an optical reflectance of each of the plurality of polymeric first layers and the plurality of polymeric second layers versus wavelength comprises a reflection band, each of the reflection bands having a FWHM of greater than about 10 nm.

### Claim 11 (depends on 10)

The multilayer optical film of claim 10, wherein for the p-polarized incident light and the first incident angle, an optical reflectance of the optical film versus wavelength comprises a reflection band having a FWHM within about 20% of the FWHM of the reflection band of the plurality of polymeric first layers; and for the p-polarized incident light and the second incident angle, an optical reflectance of the optical film versus wavelength comprises a reflection band having a FWHM different from the FWHM of the reflection band of the plurality of polymeric first layers by at least about 30%.

### Claim 12 (depends on 10)

The multilayer optical film of claim 10, for the p-polarized incident light and for at least one incident angle greater than about 30 degrees;
an optical reflectance of each of the optical film, the plurality of polymeric first layers, and the plurality of polymeric second layers versus wavelength comprises a reflection band comprising a left band edge (LBE) at a short wavelength side of the reflection band where the reflectance generally increases with increasing wavelength, and a right band edge (RBE) at a long wavelength side of the reflection band where the reflectance generally decreases with increasing wavelength, such that the RBE of the optical film substantially overlaps the RBE of one of the pluralities of first and second layers, and the LBE of the optical film substantially overlaps the LBE of the other one of the pluralities of first and second layers.

### Claim 13 (depends on 10)

The multilayer optical film of claim 10, wherein for the p-polarized incident light and for incident angles θa, θb>θa, and θc>θb, an optical reflectance of the optical film versus wavelength comprises respective first, second, and third reflection bands having respective full width at half maximums, F1, F2, and F3, wherein F3>F1>F2.

### Claim 14

A multilayer optical film comprising a plurality of alternating first and second polymeric layers disposed on, and integrally formed with, a plurality of alternating third and fourth polymeric layers, each of the two pluralities comprising at least 10 polymeric layers in total, each of the first through fourth polymeric layers having an average thickness of less than about 500 nm, such that for an unpolarized incident light in a predetermined wavelength range that is at least about 200 nm wide and is disposed between about 200 nm and about 2000 nm, an optical reflectance of the optical film versus wavelength comprises a reflection band having a full width at half maximum of less than about 100 nm for at least a first incident angle less than about 25 degrees, and for at least one first wavelength in the reflection band, the optical reflectance of the optical film is greater than about 50% for each of the first incident angle and a second incident angle greater than the first incident angle by at least about 60 degrees.

### Claim 15 (depends on 14)

The multilayer optical film of claim 14 wherein the first through fourth polymeric layers have respective refractive indices nx1 through nx4 along a same in-plane x-direction, respective refractive indices ny1 through n4 along an in-plane y-direction orthogonal to the x-direction, and respective refractive indices nz1 through nz4 along a thickness direction of the polymeric layers orthogonal to the x- and y-directions, such that for at least one wavelength in the predetermined wavelength range:
each of |nx1−nx2| and |ny1−ny2| is less than about 0.02;
nz1−nz2 is greater than about 0.03;
nx1 is less than nz1 by at least about 0.02;
nx4−nx3 is greater than about 0.03;
nz4−nz3≥nx4−nx3; and
nx3 is greater than nz3 by at least about 0.02.