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US 2024/0192591 A1Published application
Resist composition and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Takayuki Fujiwara
Life of this patent
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Abstract
A resist composition comprising an acid generator containing a sulfonium salt containing a sulfonic acid anion having a carbon atom to which an iodine atom is bonded and a sulfonium cation having formula (1).
Claims13
A resist composition comprising an acid generator containing a sulfonium salt containing a sulfonic acid anion having a carbon atom to which an iodine atom is bonded and a sulfonium cation having formula (1):
- wherein p, q, and r are each independently an integer of 0 to 3, and s is 1 or 2, provided that 1≤r+s≤3,
- R1 is a halogen atom, a trifluoromethyl group, a trifluoromethoxy group, a trifluoromethylthio group, a nitro group, a cyano group, —C(═O)—R5, —O—C(═O)—R5, or —O—R5,
- R2 and R3 are each independently a halogen atom, a trifluoromethyl group, a trifluoromethoxy group, a trifluoromethylthio group, a nitro group, a cyano group, —C(═O)—O—R4, —C(═O)—R5, —O—C(═O)—R5, —O—C(═O)—O—R5, or —O—R5,
- R4 is a C1-C10 aliphatic hydrocarbyl group, a C6-C12 aryl group, or a C4-C12 heteroaryl group, some or all of hydrogen atoms of these groups may be substituted with a halogen atom other than an iodine atom, a hydroxy group, a cyano group, a nitro group, a halogenated alkyl group, a halogenated alkoxy group, or a halogenated alkylthio group, and some of —CH2— of these groups may be substituted with an ether bond, an ester bond, a carbonyl group, or a sulfonic ester bond, provided that R4 is not an acid labile group,
- R5 is a C1-C10 hydrocarbyl group, and
- Z1 and Z2 are each independently a hydrogen atom, a halogen atom, a trifluoromethyl group, a trifluoromethoxy group, a trifluoromethylthio group, a nitro group, a cyano group, —C(═O)—O—R4, —C(═O)—R5, —O—C(═O)—R5, —O—C(═O)—O—R5, or —O—R5, and Z1 and Z2 may together form a single bond, an ether bond, a carbonyl group, —N(RN)—, a sulfide bond, or a sulfonyl group, wherein RN is a hydrogen atom or a C1-C6 saturated hydrocarbyl group.
3 more elements
Dependencies are inferred from the claim text.