Oxide phosphor, light-emitting device, and method for producing oxide phosphor
AssigneeNichia Corporation
InventorYoshinori MURAZAKI
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Abstract
Provided is an oxide phosphor having a light emission peak in a wavelength range from red light to near-infrared light. An oxide phosphor having a composition represented by Formula (1): (Li1−uM1u)2M2vM3wOx:Cry,M4z (1). wherein M1 is at least one element selected from the group consisting of Na, K, Rb and Cs; M2 is at least one element selected from the group consisting of Mg, Ca, Sr, Ba and Zn; M3 is at least one element selected from the group consisting of Si, Ge, Ti, Zr, Sn, and Hf; M4 is at least one element selected from the group consisting of Ni, Eu, Fe, Mn, Nd, Tm, Ho, Er, and Yb; and u, v, w, x, y, and z satisfy 0≤u≤1.0, 0.8≤v≤3.0, 1.8≤w≤6, 5.4≤x≤16, 0.005≤y≤1.0, and 0≤z≤0.5, respectively.
Claims11
An oxide phosphor having a composition represented by Formula (1) below:
- (Li1−uM1u)2M2vM3wOx:Cry,M4z (1)
- wherein in Formula (1), M1 is at least one element selected from the group consisting of Na, K, Rb and Cs;
- M2 is at least one element selected from the group consisting of Mg, Ca, Sr, Ba and Zn;
- M3 is at least one element selected from the group consisting of Si, Ge, Ti, Zr, Sn, and Hf;
- M4 is at least one element selected from the group consisting of Ni, Eu, Fe, Mn, Nd, Tm, Ho, Er, and Yb;
- and u, v, w, x, y, and z satisfy 0≤u≤1.0, 0.8≤v≤3.0, 1.8≤w≤6, 5.4≤x≤16, 0.005≤y≤1.0, and 0≤z≤0.5, respectively.
A method for producing an oxide phosphor, the method comprising:
- preparing a raw material mixture by adjusting and mixing a first compound containing Li, a second compound containing at least one second element M2 selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, a third compound containing at least one third element M3 selected from the group consisting of Si, Ge, Ti, Zr, Sn, and Hf, a fourth compound containing Cr, and optionally, a fifth compound containing at least one first element M1 selected from the group consisting of Na, K, Rb, and Cs or a sixth compound containing at least one fourth element M4 selected from the group consisting of Ni, Eu, Fe, Mn, Nd, Tm, Ho, Er, and Yb such that, when a total molar ratio of the Li and the first element M1 contained as necessary per one mole of a composition of the oxide phosphor is 2, a molar ratio of the Li is a product of 2 and a number in a range of 0 to 1.0, a molar ratio of the first element M1 is a product of 2 and a variable u within a range of 0 to 1.0, a molar ratio of a total of the second element M2 is a variable v within a range of 0.8 to 3.0, a molar ratio of the third element M3 is a variable w within a range of 1.8 to 6, a molar ratio of the Cr is a variable y in a range of 0.005 to 1.0, and a molar ratio of the fourth element M4 is a variable z in a range of 0 to 0.5;
- and
- obtaining an oxide phosphor by heat-treating the raw material mixture in an atmosphere containing oxygen at a temperature in a range of 800° C. to 1200° C.,
- wherein at least one compound selected from the group consisting of the first compound, the second compound, the third compound, and the fourth compound is an oxide.
Dependencies are inferred from the claim text.