Sulfide solid electrolyte material, battery, and method of manufacturing sulfide solid electrolyte material
AssigneesToyota Jidosha Kabushiki Kaisha, Tokyo Institute of Technology
InventorsKeiichi MINAMI, Ryoji KANNO, Satoshi HORI
Life of this patent
Estimating the term…
Abstract
A sulfide solid electrolyte material contains element M1, element M2, element M3 and element S. Element M1 is at least one type selected from the group consisting of Li, Na, K, Mg Ca and Zn, and contains at least one of Li and Na. Element M2 is at least one type selected from the group consisting of P, Sb, Si, Ge, Sn, B, Al, Ga, In, Ti, Zr and V, and contains at least P.
Claims14
A sulfide solid electrolyte material, comprising an element M1, an element M2, an element M3 and an element S, wherein:
- the element M1 is at least one selected from the group consisting of Li, Na, K, Mg, Ca and Zn, and contains at least one of Li or Na;
- the element M2 is at least one selected from the group consisting of P, Sb, Si, Ge, Sn, B, Al, Ga, In, Ti, Zr and V, and contains at least P;
- the element M3 is at least one selected from transition elements of group 3 to group 12;
- and
- the sulfide solid electrolyte material has a peak at a position of 2θ=29.58°±0.50°, in X-ray diffraction measurement using a CuKα beam, or
- the sulfide solid electrolyte material does not have a peak at a position of 2θ=27.33°±0.50°, in X-ray diffraction measurement using a CuKα beam, or
- in a case in which the sulfide solid electrolyte material has a peak at a position of 2θ=27.33°±0.50°, if a diffracted intensity of the peak at 2θ=29.58°±0.50° is IA and a diffracted intensity of the peak at 2θ=27.33°±0.50° is IB, a value of IB/IA is less than 1.00.
A sulfide solid electrolyte material, comprising octahedrons O structured from an element M1 and an element S, tetrahedrons T1 structured from an element M2a and the element S, and tetrahedrons T2 structured from the element S and at least one selected from the group consisting of an element M2b and an element M3, and having, as a main body, a crystal structure in which the tetrahedrons T1 and the octahedrons O share edges, and the tetrahedrons T2 and the octahedrons O share vertices, wherein:
- the element M1 is at least one selected from the group consisting of Li, Na, K, Mg, Ca and Zn, and contains at least one of Li or Na;
- and
- each of the element M2a and the element M2b is independently at least one selected from the group consisting of P, Sb, Si, Ge, Sn, B, Al, Ga, In, Ti, Zr and V, and contain at least P;
- and
- the element M3 is at least one selected from transition elements of group 3 to group 12.
Dependencies are inferred from the claim text.