Sulfobetaine-modified polyurethane or polyurea foam
Assignee3M Innovative Properties Company
InventorsTony R. Carrozzella, Kent E. Nielsen
Life of this patent
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Abstract
A hydrophilic foam comprises a polymer formed from a betaine prepolymer that is a reaction product of a betaine of formula (I) with one or more polyether glycols and a polyfunctional isocyanate compound of formula (II), (I) wherein R1, R2, R3, and R4 are each hydrocarbon groups having from 1 to 4 carbon atoms, A− is an anionic functional group, and X+ is a cationic atom, (II) wherein R5 is a linear or branched aliphatic hydrocarbon group having from 2 to 12 carbon atoms, or a 5- or 6-membered aliphatic or aromatic carbocyclic group having from 5 to 50 carbon atoms, and b is an integer having a value of 1, 2, or 3.
Claims19
A hydrophilic foam comprising a polymer formed from a betaine prepolymer that is a reaction product of a betaine of formula (I) with one or more polyether glycols and a polyfunctional isocyanate compound of formula (II),
- wherein R1, R2, R3, and R4 are each hydrocarbon groups having from 1 to 4 carbon atoms, A− is an anionic functional group, and X+ is a cationic atom,
- OCN—R5—(NCO)b (II)
- wherein R5 is a linear or branched aliphatic hydrocarbon group having from 2 to 12 carbon atoms, or a 5- or 6-membered aliphatic or aromatic carbocyclic group having from 5 to 50 carbon atoms, and
- b is an integer having a value of 1, 2, or 3.
A hydrophilic foam comprising a polymer formed from a betaine prepolymer of formula (I):
- wherein A− is an anionic functional group,
- R1, R2, and R3 are each hydrocarbon groups having from 1 to 4 carbon atoms,
- R5 is a linear or branched aliphatic hydrocarbon group having from 2 to 12 carbon atoms, or a 5- or 6-membered aliphatic or aromatic carbocyclic group having from 5 to 50 carbon atoms,
- b is an integer having a value of 1, 2, or 3, and
- c is the degree of polymerization of the betaine prepolymer, which is an integer having a value of 1-5.
A method comprising the steps of:
- (a) reacting a betaine of formula (I) with one or more polyether glycols and a polyfunctional isocyanate compound of formula (II) to provide a hydrophilic prepolymer,
- wherein R1, R2, R3, and R4 are each hydrocarbon groups having from 1 to 4 carbon atoms,
- A− is an anionic functional group, and
- X+ is a cationic atom,
- OCN—R5—(NCO)b (II)
- wherein R5 is a is a linear or branched aliphatic hydrocarbon group having from 2 to 12 carbon atoms, or a 5- or 6-membered aliphatic or aromatic carbocyclic group having from 5 to 50 carbon atoms, and
- b is an integer having a value of 1, 2, or 3;
- (b) polymerizing and foaming the hydrophilic prepolymer of step (a) to provide a hydrophilic foam.
19-33. (canceled)
Dependencies are inferred from the claim text.