Spherical catalyst components for olefin polymerization
AssigneeW.R. Grace & Co.-Conn.
InventorsVladimir P. MARIN, Ahmed HINTOLAY
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Abstract
A process of producing a spherical catalyst component for use in producing polyolefin polymers includes dissolving a magnesium halide compound in a solvent to form a homogeneous solution, the solvent comprising an alcohol; and treating the homogeneous solution with a titanium compound in the presence of a surfactant, a supportive electron donor, and an internal electron donor to form a solid catalyst component comprising a magnesium halide compound base incorporating a titanium unit, the supportive electron donor, and the internal electron donor; wherein the catalyst component comprises particles having a substantially spherical shape and a D50 from about 3 μm to about 150 μm.
Claims27
A process of producing a spherical catalyst component for use in producing polyolefin polymers, the process comprising:
- a) dissolving a magnesium halide compound in a solvent to form a homogeneous solution, the solvent comprising an alcohol;
- b) treating the homogeneous solution with a first titanium compound in the presence of a surfactant, a supportive electron donor, and optionally a first internal electron donor to form a solid precipitate;
- c) treating the solid precipitate with a second titanium compound in the presence a second internal electron donor to form a spherical catalyst component including a magnesium halide compound base incorporating the titanium unit, the supportive electron donor, the second internal electron donor, and optionally the first electron donor;
- and
- wherein the spherical catalyst component comprises particles having a substantially spherical shape and exhibiting a D50 from about 3 μm to about 150 μm.
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Dependencies are inferred from the claim text.