Resin-extended modified diene rubber
AssigneeCompagnie Generale Des Etablissements Michelin
InventorsFLORENT VAULTIER, KEVIN ROOS, FABIEN BARRET
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Abstract
A resin-extended modified diene elastomer is based on a plasticizing resin and a diene elastomer having a number-average molar mass before modification Mn1 and a number-average molar mass Mn2 after modification, Mn1 and Mn2 being measured by triple detection size exclusion chromatography, the modified diene elastomer comprising branched chains corresponding to the following general formula (I) the modified diene elastomer having an Mn2 of greater than or equal to 200 000 g/mol and has an Mn2/Mn1 ratio of strictly greater than 1.00.
Claims17
-15. (canceled)
A resin-extended modified diene elastomer based on:
- a plasticizing resin;
- and
- a diene elastomer having a number-average molar mass before modification Mn1 and a number-average molar mass Mn2 after modification, Mn1 and Mn2 being measured by triple detection size exclusion chromatography,
- wherein the resin-extended modified diene elastomer comprises branched chains and corresponds to the following general formula (I)
- in which:
- E represents a branch of the diene elastomer;
- Z represents an atom selected from the group consisting of P, Si and Sn;
- R1 represents, independently at each occurrence, a hydrogen atom, a C1-C10 alkyl or a C6-C12 aryl;
- R2 represents, independently at each occurrence, a C1-C10 alkyl;
- R3 represents a saturated or unsaturated, cyclic or non-cyclic, divalent C1-C18 aliphatic hydrocarbon radical, or a divalent C6-C18 aromatic hydrocarbon radical;
- Y represents a hydrogen atom or a function capable of interacting with a reinforcing filler;
- m is an integer being equal to 2, 3 or 4;
- n is an integer being equal to 0, 1 or 2;
- p is an integer being equal to 0, 1 or 2;
- q is an integer being equal to 0 or 1;
- with the proviso that
- when Z=P then q=0, m=2 or 3 and m+n+p=3;
- when Z=Sn then q=0 and m+n+p=4;
- and
- when Z=Si then m+n+p+q=4, and
- wherein the resin-extended modified diene elastomer has an Mn2 of greater than or equal to 200,000 g/mol and an Mn2/Mn1 ratio of strictly greater than 1.00.
Dependencies are inferred from the claim text.