Reactor apparatus, vinyl-based polymer manufacturing method, and method for producing vinyl-based polymer
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsHiroaki SAITO, Eisuke GOTO, Yasunori HAMAGUCHI
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Abstract
A representative point of each of the plurality of first cooling pipes in a plane substantially perpendicular to an extending direction of the straight body is located substantially on a circumference of any of a plurality of virtual circles arranged substantially concentrically in the substantially perpendicular plane. A number Nc [units] of the plurality of virtual circles and a proportion CZ [mg-dispersing aid/kg-monomer] of a mass of the dispersing aid to a mass of one or more types of monomers to be materials of the polymer satisfy a particular relationship.
Claims18
A reactor apparatus of batch type used for producing a polymer by suspension polymerization using a dispersing aid, the reactor apparatus comprising:
- a reactor having a straight body having a tubular shape;
- a plurality of first cooling pipes arranged inside the reactor, for circulating a coolant;
- and
- an agitation shaft which is arranged inside the reactor, is attached with an agitating blade, and is configured to be rotatable, wherein
- a representative point of each of the plurality of first cooling pipes in a plane substantially perpendicular to an extending direction of the straight body is located substantially on a circumference of any of a plurality of virtual circles arranged substantially concentrically in the substantially perpendicular plane, and
- when a number Nc [units] of the plurality of virtual circles is 1, 2, or 3, the number Nc [units] of the plurality of virtual circles and a proportion CZ [mg-dispersing aid/kg-monomer] of a mass of the dispersing aid to a mass of one or more types of monomers to be materials of the polymer satisfy a relationship represented by following Expression A1
- 15Nc+300<CZ<175Nc+2000. (Expression A1)
A reactor apparatus of batch type used for producing a polymer by suspension polymerization using a dispersing aid, the reactor apparatus comprising:
- a reactor having a straight body having a tubular shape;
- a plurality of first cooling pipes arranged inside the reactor, for circulating a coolant;
- an agitation shaft which is arranged inside the reactor, is attached with one or more agitating blades, and configured to be rotatable;
- and
- a dispersing aid input unit which inputs the dispersing aid into the reactor, wherein
- a representative point of each of the plurality of first cooling pipes in a plane substantially perpendicular to an extending direction of the straight body is located substantially on a circumference of any of a plurality of virtual circles arranged substantially concentrically in the substantially perpendicular plane, and
- when a number Nc [units] of the plurality of virtual circles is 1, 2, or 3, the dispersing aid input unit inputs the dispersing aid so that the number Nc [units] of the plurality of virtual circles and a proportion CZ [mg-dispersing aid/kg-monomer] of a mass of the dispersing aid to a mass of one or more types of monomers to be materials of the polymer satisfy a relationship represented by following Expression A1
- 15Nc+300<CZ<175Nc+2000. (Expression A1)
A method for producing a vinyl-based polymer by a suspension polymerization method by using a reactor apparatus of batch type, wherein
- the reactor apparatus includes
- a reactor having a straight body having a tubular shape,
- a plurality of first cooling pipes arranged inside the reactor, for circulating a coolant, and
- an agitation shaft which is arranged inside the reactor, is attached with an agitating blade, and is configured to be rotatable, wherein
- a representative point of each of the plurality of first cooling pipes in a plane substantially perpendicular to an extending direction of the straight body is located substantially on a circumference of any of a plurality of virtual circles arranged substantially concentrically in the substantially perpendicular plane, and
- the method comprising:
- inputting a material by inputting a vinyl-based monomer, an aqueous media, and a dispersing aid into the reactor;
- and
- polymerizing the vinyl-based monomer to produce a vinyl-based polymer, wherein
- the inputting the material includes
- inputting the dispersing aid such that when a number Nc [units] of the plurality of virtual circles is 1, 2, or 3, the number Nc [units] of the plurality of virtual circles and a proportion CZ [mg-dispersing aid/kg-monomer] of a mass of the dispersing aid to a mass of the vinyl-based monomer satisfy a relationship represented by following Expression A1
- 15Nc+300<CZ<175Nc+2000. (Expression A1)
Dependencies are inferred from the claim text.