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US 2024/0058795 A1Published application
Hydrogenation catalyst with improved sulfur resistance and method for producing same
AssigneeHanwha Solutions Corporation
InventorsYoung Hee LEE, Woo Jin PARK, Bong Sik JEON, Eui Geun JUNG
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Abstract
The present invention relates to a hydrogenation catalyst with improved sulfur resistance and a method for producing the same. More specifically, the present invention comprises cerium and copper to enhance resistance to sulfur, that is, resistance to sulfur poisoning, thereby extending the lifespan and improving activity of the catalyst, which is be used in the hydrogenation of petroleum resin.
Claims17
A hydrogenation catalyst comprising:
- 40 to 80 parts by weight of nickel, 0.01 to 5 parts by weight of copper and 0.05 to 5 parts by weight of cerium as catalyst activation components;
- and 10 to 30 parts by weight of silica as a carrier.
A method for producing a hydrogenation catalyst, comprising:
- preparing a first solution by dissolving a nickel precursor in a solvent so as to have a weight concentration (g/L) of nickel in the range of 25 to 100 in the first solution;
- preparing a second solution by adding a copper precursor and a cerium precursor to the first solution so as to have a weight concentration (g/L) of copper in the range of 0.01 to 5 and a weight concentration (g/L) of cerium in the range of 0.05 to 5 in the second solution;
- preparing a third solution by adding a silica carrier to the second solution and dispersing the silica carrier therein so as to have a weight concentration (g/L) of silica in the range of 5 to 30 in the third solution;
- placing the third solution in a precipitation bottle, followed by stirring and heating the third solution to a temperature of 50° C. to 120° C.;
- preparing a catalyst by adding a pH regulator to the third solution to precipitate and deposit the precursors on the silica carrier;
- washing and filtering the catalyst, followed by drying the filtered catalyst;
- and
- activating the dried catalyst through reduction of the dried catalyst.
5 more elements
Dependencies are inferred from the claim text.