Solid electrolyte, method of producing solid electrolyte, and battery
AssigneesNGK Insulators, Ltd., Nagoya Institute of Technology
InventorsYosuke SATO, En YAGI, Satoshi OZAKI, Toshihiro YOSHIDA, Yuji KATSUDA, Mizuki HIROSE, Reona MIYAZAKI
Life of this patent
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Abstract
A solid electrolyte is composed primarily of a component expressed by a composition formula of Lia+dMbXcAeOf by using values a to f that are greater than 0, where M is an element serving as a trivalent cation, X is a halogen element, and A is a sulfur element or a phosphorus element, wherein 0.8c≤(a+3b)≤1.2c and 1.6f≤(d+n×e)≤2.4f are satisfied, where when A is a sulfur element, n is 4 or 6, and when A is a phosphorus element, n is 5.
Claims18
A solid electrolyte composed primarily of a component expressed by a composition formula of Lia+dMbXcAeOf by using values a to f that are greater than 0, where M is an element serving as a trivalent cation, X is a halogen element, and A is a sulfur element or a phosphorus element,
- wherein 0.8c≤(a+3b)≤1.2c and 1.6f≤(d+n×e)≤2.4f are satisfied, where when A is a sulfur element, n is 4 or 6, and when A is a phosphorus element, n is 5.
A method of producing a solid electrolyte, comprising:
- a) preparing a compound expressed by a composition formula of LiaMbXc and a compound expressed by a composition formula of LidAeOf by using values a to f that are greater than 0, where M is an element serving as a trivalent cation, X is a halogen element, A is a sulfur element or a phosphorus element, the values a to f satisfy 0.8c≤(a+3b)≤1.2c and 1.6f≤(d+n×e)≤2.4f, and when A is a sulfur element, n is 4 or 6, and when A is a phosphorus element, n is 5;
- and
- b) subjecting LiaMbXc and LidAeOf to a mechanical milling process,
- wherein, in said operation b), a ratio of the amount of substance of LidAeOf to a total of the amount of substance of LiaMbXc and the amount of substance of LidAeOf is lower than or equal to 85%.
A method of producing a solid electrolyte, comprising:
- a) preparing a first compound that is LiX, a second compound that is MX3, and a third compound composed of Li, A, and O, where X is a halogen element, M is an element serving as a trivalent cation, and A is a sulfur element or a phosphorus element;
- and
- b) subjecting said first compound, said second compound, and said third compound to a mechanical milling process,
- wherein, in said operation a), 0.8c≤(a+3b)≤1.2c and 1.6f≤(d+n×e)≤2.4f are satisfied when a ratio of the amounts of substance of Li, M, and X in a mixture of said first compound and said second compound and the amounts of substance of Li, A, and O in said third compound is expressed as a:b:c:d:e:f by using values a to f that are greater than 0, where when A is a sulfur element, n is 4 or 6, and when A is a phosphorus element, n is 5, and
- 0<e/(c+e)≤0.5 is further satisfied.
Dependencies are inferred from the claim text.