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US 2023/0416634 A1Published application
Compressor oils with high viscosity index
AssigneeEvonik Operations GmbH
InventorsThomas SCHIMMEL, Frank-Olaf Mähling, Lucas Voigt
Life of this patent
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Abstract
Polyalkyl (meth)acrylates are useful in compressor oils. A method of increasing the energy efficiency of a compressor involves operating the compressor with a compressor oil containing a polyalkyl (meth)acrylate-based viscosity index improver.
Claims20
1:
- A method of increasing the energy efficiency of a compressor, the method comprising:
- operating the compressor with a compressor oil, wherein the compressor oil comprises:
- (i) 1 wt. % to 30 wt. % of a polyalkyl methacrylate-based viscosity index improver comprising:
- (a) 0 wt. % to 25 wt. % of methyl methacrylate;
- (b) 75 wt. % to 100 wt. % of at least one straight-chained or branched C10-18 alkyl (meth)acrylate;
- and
- (c) 0 wt. % to 2 wt. % of at least one straight-chained or branched C5-9 alkyl (meth)acrylate or at least one straight-chained or branched C20-24 alkyl (meth)acrylate,
- wherein a weight average molecular weight (Mw) of the polyalkyl (meth)acrylate-based viscosity index improver is in a range of 5,000 g/mol to 400,000 g/mol;
- (ii) 70 wt. % to 99 wt. % of a base oil, wherein the base oil is an oil of American Petroleum Institute (API) group II, III, IV, or V, or a mixture thereof;
- and
- (iii) optionally, up to 2.5 wt. % of a performance package comprising one or more further additives,
- wherein the compressor oil has a viscosity index of at least 140.
9 more elements
2:
- The method according to claim 1, wherein the polyalkyl methacrylate-based viscosity index improver comprises:
- (a) 0.2 wt. % of the methyl methacrylate;
- (b) 75 wt. % to 99.8 wt. % of the at least one C10-18 alkyl (meth)acrylate;
- and
- (c) 0 wt. % to 2 wt. % of the at least one straight-chained or branched C5-9 alkyl (meth)acrylate or the at least one straight-chained or branched C20-24 alkyl (meth)acrylate.
2 more elements
3:
- The method according to claim 1, wherein the weight average molecular weight (Mw) of the polyalkyl (meth)acrylate-based viscosity index improver is in a range of 5,000 g/mol to 200,000 g/mol.
4:
- The method according to claim 1, wherein the performance package (iii) comprises at least an antiwear agent, an anticorrosion agents and an antioxidant.
5:
- The method according to claim 1, wherein the compressor is selected from the group consisting of household or domestic refrigeration units, air compressors, and carbon dioxide compressors.
6:
- The method according to claim 1, wherein the compressor is a household or domestic refrigeration unit, the base oil (ii) is an API group IV or V oil, or a mixture thereof, and the compressor oil has a kinematic viscosity at 40° C. in a range of 2.88 and 7.48 cSt.
7:
- The method according to claim 6, wherein the household or domestic refrigeration unit uses isobutane or propane as refrigerant.
8:
- The method according to claim 1, wherein the compressor is a household or domestic refrigeration unit using isobutane or propane as refrigerant, the method comprising:
- operating the refrigeration unit with the compressor oil, wherein the compressor oil comprises:
- (i) 1 wt. % to 10 wt. % of the polyalkyl methacrylate-based viscosity index improver comprising:
- (a) 0.2 wt. % to 25 wt. % of the methyl methacrylate;
- and
- (b) 75 wt. % to 99.8 wt. % of the at least one C10-18 alkyl (meth)acrylate,
- wherein the weight average molecular weight (Mw) of the polyalkyl (meth)acrylate-based viscosity index improver is in a range of 5,000 g/mol to 200.000 g/mol;
- (ii) 90 wt. % to 99 wt. % of an API group IV or V base oil, or a mixture thereof;
- and
- (iii) 0 wt. % to 2.5 wt. % of a zinc-free performance package comprising at least an antiwear agent, an anticorrosion agent, and an antioxidant,
- wherein the compressor oil has a kinematic viscosity at 40° C. in the range of 2.88 and 7.48 cSt and a viscosity index of at least 140.
8 more elements
9:
- The method according to claim 6, wherein the base oil (ii) is selected from naphthenic base oils having a CN value of more than 42%.
10:
- The method according to claim 6, wherein the compressor oil has a pour point of −60° C. or lower.
11:
- The method according to claim 1, wherein the compressor is an air compressor, the base oil (ii) is an API group II, III, or IV oil, or a mixture thereof, and the compressor oil has a kinematic viscosity at 40° C. in a range of 28.8 and 74.8 cSt.
12:
- The method according to claim 1, wherein the compressor is an air compressor, the method comprising:
- operating the air compressor with the compressor oil, wherein the compressor oil comprises:
- (i) 1 wt. % to 20 wt. % of the polyalkyl methacrylate-based viscosity index improver comprising:
- (a) 0.2 wt. % to 25 wt. % of the methyl methacrylate;
- (b) 75 wt. % to 99.8 wt. % of the at least one C10-18 alkyl (meth)acrylate;
- and
- (c) 0 wt. % to 2 wt. % of the at least one straight-chained or branched C5-9 alkyl (meth)acrylate or the at least one straight-chained or branched C20-24 alkyl (meth)acrylate,
- wherein the weight average molecular weight (Mw) of the polyalkyl (meth)acrylate-based viscosity index improver is in the range of 5,000 to 400,000 g/mol;
- (ii) 80 wt. % to 99 wt. % of an API group II, III, or IV base oil, or a mixture thereof;
- and
- (iii) 0 wt. % to 2.5 wt. % of a zinc-free performance package comprising at least an antiwear agent, an anticorrosion agent, and an antioxidant,
- wherein the compressor oil has a kinematic viscosity at 40° C. in the range of 28.8 and 74.8 cSt and a viscosity index of at least 140.
9 more elements
13:
- The method according to claim 11, wherein the compressor oil has a pour point of −33° C. or lower.
14:
- The method according to claim 1, wherein the compressor is a carbon dioxide compressor, the base oil (ii) is an API group III, IV, or V oil, or a mixture thereof, and the compressor oil has a kinematic viscosity at 40° C. in a range of 41.4 and 110 cSt.
15:
- The method according to claim 1, wherein the compressor is a carbon dioxide compressor, the method comprising:
- operating the carbon dioxide compressor with the compressor oil, wherein the compressor oil comprises:
- (i) 1 wt. % to 20 wt. % of the polyalkyl methacrylate-based viscosity index improver comprising:
- (a) 0.2 wt. % to 25 wt. % of the methyl methacrylate;
- and
- (b) 75 wt. % to 99.8 wt. % of the at least one C10-18 alkyl (meth)acrylate,
- wherein the weight average molecular weight (Mw) of the polyalkyl (meth)acrylate-based viscosity index improver is in the g range of 5,000 g/mol to 100,000 g/mol;
- (ii) 80 wt. % to 95 wt. % of a polyolester base oil or g mixture of different polyester base oils;
- and
- (iii) 0 wt. % to 2.5 wt. % of a zinc-free performance package comprising at least an antiwear agent, an anticorrosion agent, and an antioxidant,
- wherein the compressor oil has a kinematic viscosity at 40° C. in the range of 41.4 and 110 cSt, and a viscosity index of at least 140.
8 more elements
16:
- The method according to claim 1, wherein the compressor is a carbon dioxide compressor, the method comprising:
- operating the carbon dioxide compressor with the compressor oil, wherein the compressor oil comprises:
- (i) 1 wt. % to 30 wt. % the polyalkyl methacrylate-based viscosity index improver comprising:
- (a) 0.2 wt. % to 25 wt. % of the methyl methacrylate;
- and
- (b) 75 wt. % to 99.8 wt. % of the at least one C10-18 alkyl (meth)acrylate,
- wherein the weight average molecular weight (Mw) of the polyalkyl (meth)acrylate-based viscosity index improver is in a range of 5,000 g/ml to 100,000 g/mol;
- (ii) 80 wt. % to 99 wt. % of a polyalphaolefin base oil or mixture of different polyalphaolefin base oils;
- and
- (iii) 0 wt. % to 2.5 wt. % of a zinc-free performance package comprising at least an antiwear agent, an anticorrosion agent, and an antioxidant,
- wherein the compressor oil has a kinematic viscosity at 40° C. in the range of 41.4 and 110 cSt and a viscosity index of at least 140.
8 more elements
17:
- The method according to claim 1, wherein the compressor oil has a viscosity index of at least 180.
18:
- The method according to claim 2, wherein the polyalkyl methacrylate-based viscosity index improver comprises:
- (a) 4 wt. % to 16 wt. % of the methyl methacrylate;
- (b) 84 wt. % to 96 wt. % of the at least one C10-18 alkyl methacrylate;
- and
- (c) 0 wt. % to 2 wt. % of the at least one straight-chained or branched C5-9 alkyl (meth)acrylate or the at least one straight-chained or branched C20-24 alkyl (meth)acrylate.
2 more elements
19:
- The method according to claim 4, wherein the performance package (iii) is zinc-free.
20:
- The method according to claim 4, wherein the performance package (iii) is ashless.