Metallocene polypropylene prepared using aromatic solvent-free supports

A supported catalyst composition comprising aromatic-solvent-free support and catalyst compound represented by the Formula (I):

• wherein:
• M is a Group 4 metal;
• T is a bridging group;
• each of X1 and X2 is a univalent anionic ligand, or X1 and X2 are joined to form a metallocycle ring;
• R1 is hydrogen, a halogen, an unsubstituted C1-C40 hydrocarbyl, a C1-C40 substituted hydrocarbyl, an unsubstituted C4-C62 aryl, a substituted C4-C62 aryl, an unsubstituted C4-C62 heteroaryl, a substituted C4-C62 heteroaryl, —NR′2, —SR′, —OR, —SiR′3, —OSiR′3, —PR′2, or —R″—SiR′3, where R″ is C1-C10 alkyl and each R′ is hydrogen, halogen, C1-C10 alkyl, or C6-C10 aryl;
• R3 is an unsubstituted C4-C62 cycloalkyl, a substituted C4-C62 cycloalkyl, an unsubstituted C4-C62 aryl, a substituted C4-C62 aryl, an unsubstituted C4-C62 heteroaryl, or a substituted C4-C62 heteroaryl;
• each of R2 and R4 is independently hydrogen, a halogen, an unsubstituted C1-C40 hydrocarbyl, a C1-C40 substituted hydrocarbyl, an unsubstituted C4-C62 aryl, a substituted
• C4-C62 aryl, an unsubstituted C4-C62 heteroaryl, a substituted C4-C62 heteroaryl, —NR′2, —SR′,
• —OR, —SiR′3, —OSiR′3, —PR′2, or —R″—SiR′3, wherein R″ is C1-C10 alkyl and each R′ is hydrogen, halogen, C1-C10 alkyl, or C6-C10 aryl;
• each of R5, R6, R7, and R8 is independently hydrogen, a halogen, an unsubstituted
• C1-C40 hydrocarbyl, a C1-C40 substituted hydrocarbyl, an unsubstituted C4-C62 aryl, a substituted C4-C62 aryl, an unsubstituted C4-C62 heteroaryl, a substituted C4-C62 heteroaryl,
• —NR′2, —SR′, —OR, —SiR′3, —OSiR′3, —PR′2, or —R″—SiR′3, wherein R″ is C1-C10 alkyl and each R′ is hydrogen, halogen, C1-C10 alkyl, or C6-C10 aryl, or one or more of R5 and R6, R6 and R7, or R7 and R8 can be joined to form a substituted or unsubstituted C4-C62 saturated or unsaturated cyclic or polycyclic ring structure, or a combination thereof, where optionally R6 and R7 do not combine to form a six membered aromatic ring;
• and
• J1 and J2 are joined to form a substituted or unsubstituted C4-C62 saturated or unsaturated cyclic or polycyclic ring structure, or a combination thereof, provided that J1 and J2 together with the two carbons they are bound to on the indenyl group form at least one saturated ring.