Method for synthesis of monomer for single-ion battery
OwnerQiujie ZHAO, Siwei LIANG +3inventors
InventorsQiujie ZHAO, Siwei LIANG, Jin YANG, Sarah DEGRAS, Patrick LEBLANC
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Abstract
The present technology relates to methods for the synthesis of a lithium single-ion monomer which comprises simultaneously reacting a sulfonyl chloride compound with i) a fluorinated sulfonamide compound and ii) a compound that is suitable to act as a quenching base and a lithium cation source. The simultaneous reaction of sulfonyl chloride with the fluorinated sulfonamide compound and the compound that is suitable to act as a quenching base and a lithium cation source yields the single-ion monomer.
Claims19
A method for the synthesis of a lithium single-ion monomer, the method comprising simultaneously reacting a sulfonyl chloride compound with:
- i) a fluorinated sulfonamide compound;
- and
- ii) a compound that is suitable to act as a quenching base and a lithium cation source;
- wherein the simultaneous reaction of sulfonyl chloride with the fluorinated sulfonamide compound and the compound that is suitable to act as a quenching base and a lithium cation source yields the single-ion monomer;
- wherein the sulfonyl chloride compound is of formula:
- wherein
- R1 and R2 are each independently H or F;
- R3 is H, F, CN or CH3;
- R4 is an ester group, a phenyl group with L1 substituted at ortho, para, or meta position, a fully or partially fluorinated phenyl group with L1 substituted at ortho, para or meta position, an amide group, a carbonate group, or an ether group;
- and
- L1 is a n-alkyl group, a fluorinated alkyl group, a branched alkyl group, an ethylene oxide linker, a fluorinated ethylene oxide linker, a cycloalkyl group, a fluorinated cycloalkyl group, or L1 is absent.
A method for the synthesis of a lithium single-ion monomer, the method comprising:
- 1) obtaining a sulfonyl chloride compound from a sulfonate;
- 2) simultaneously reacting the sulfonyl chloride compound with:
- i) a fluorinated sulfonamide compound and
- ii) a compound that is suitable to act as a quenching base and a lithium cation source to obtain unpurified lithium single-ion monomer;
- and
- 3) purifying the unpurified lithium single-ion monomer.
Dependencies are inferred from the claim text.