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US 2023/0357115 A1Published application
Phospholane-phosphite ligands for alkene hydroformylation catalysts
AssigneeEastman Chemical Company
InventorsMesfin Ejerssa Janka, Jose Antonio Fuentes-Garcia, Matthew Clarke
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Abstract
Ligands for use with catalyst compositions used in hydroformylation reactions are described herein. The ligands are used with various solvents and achieve an increase in isoselectivity with an increase in temperature.
Claims18
A phospholane-phosphite ligand having the general formula I:
- wherein:
- R1 and R2 are independently selected from H, or substituted and unsubstituted, aryl, alkyl, aryloxy or cycloalkyl groups containing from 1 to 40 carbon atoms;
- R3, R4 and R5 are independently selected from H, F, Cl, Br, or substituted and unsubstituted, aryl, alkyl, alkoxy, trialkylsilyl, triarylsilyl, aryldialkylsilyl, diarylalkylsilyl and cycloalkyl groups containing from 1 to 20 carbon atoms, wherein the silicon atom of the alkylsilyl is in the alpha position of the substituent;
- and
- R6 and R7 are independently selected from H, F, Cl, Br, alkyl groups containing from 1 to 10 carbon atoms, halogenated alkyl groups, or aryl groups containing from 1 to 20 carbon atoms.
2 more elements
Dependencies are inferred from the claim text.