Urea urethane compounds
AssigneeBASF SE
InventorsHuiguang KOU, Matthias MAIER, Isabell HERZOG, Clemens AUSCHRA
Life of this patent
Estimating the term…
Abstract
The presently claimed invention relates to urea urethane compounds obtainable by reacting toluene diisocyanate with a mixture of monohydroxy alcohols followed by reaction with a diamine. The presently claimed invention provides a process for preparing the urea urethane compounds, liquid compositions comprising the urea urethane compounds and the use of the urea urethane compounds as a thickening and thixotropic agent for water based and solvent based paint and coating formulations, lacquer, varnish, paper coating, wood coating, adhesive, ink, cosmetic formulation, detergent formulation, textile and drilling muds plaster formulations, PVC plastisol and cement formulations.
Claims16
-15. (canceled)
A urea urethane compound obtained by
- (i) reacting
- a. toluene diisocyanate with
- b. a mixture of monohydroxy alcohols comprising
- (b1) at least one monohydroxy alcohol of formula (I),
- R1—OH (I),
- wherein
- R1 is selected from linear or branched, substituted or unsubstituted C4-C22 alkyl, linear or branched, substituted or unsubstituted C4-C22 alkenyl, substituted or unsubstituted C6-C12 cycloalkyl, linear or branched, substituted or unsubstituted C7-C24 aralkyl, and substituted or unsubstituted C6-C24 aryl,
- a radical of formula R11(O—CnH2n)x—,
- a radical of formula R11[O—C(═O)—CvH2v]x—, and
- a radical of formula R11(O—CnH2n)x−1 [O—C(═O)—CvH2v]x—,
- wherein
- R11 is selected from linear or branched, substituted or unsubstituted C4-C22 alkyl, linear or branched, substituted or unsubstituted C4-C22 alkenyl, substituted or unsubstituted C6-C12 cycloalkyl, linear or branched, substituted or unsubstituted C7-C24 aralkyl, and substituted or unsubstituted C6-C24 aryl,
- n is an integer from 2 to 4,
- x is an integer from 1 to 15, and
- v is an integer from 4 to 6;
- and
- (b2) at least one monohydroxy alcohol of formula (II)
- R2—OH (II),
- wherein R2 is a radical of formula CpH2p+1 (O—CqH2q)r—,
- p is an integer from 1 to 3,
- q is an integer from 2 to 4 and
- r is an integer from 1 to 50,
- wherein the molar ratio of the at least one monohydroxy alcohol of formula (I) to the at least one monohydroxy alcohol of formula (II) is in the range of 10:1 to 1:10, and
- the molar ratio of the total amount of the mixture of monohydroxy alcohols to the toluene diisocyanate is in the range of >1.0:1.0 to ≤1.5:1.0;
- to obtain a mixture comprising at least two monoisocyanate adducts;
- (ii) reacting the mixture comprising at least two monoisocyanate adducts obtained in step (i) with at least one diamine to obtain the urea urethane compound.
Dependencies are inferred from the claim text.