Polymerizable liquid crystal material and polymerized liquid crystal film
AssigneeMerck Patent GmbH
InventorsStephen MULCAHY, Owain Llyr PARRI, Sarabjot KAUR
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Abstract
The invention relates to a polymerizable LC material comprising one or more reactive mesogenic compounds, one or more chiral compounds and one or more compounds of formula I, wherein the individual radicals have one of the meaning as given in the claims. Furthermore, the present invention relates also to a method for its preparation, a polymer film with improved thermal and UV stability obtainable from a corresponding polymerizable LC material, to a method of preparation of such polymer film, and to the use of such polymer film and said polymerizable LC material in optical, electro-optical, decorative or security devices.
Claims20
A polymerizable liquid crystal material comprising one or more reactive mesogenic compounds, one or more chiral compounds and one or more compounds of formula I,
- wherein
- R1 denotes each and independently from another, an alkyl radical, or aryl radicals, but at least 80% of the radicals R1 are methyl radicals, and
- R2 denotes each and independently from another
- (a)
- wherein
- R3 is denotes each and independently from another a hydrogen or alkyl radical,
- R4 denotes each and independently from another is a hydrogen, alkyl or carboxyl radical
- c denotes integer from 1 to 20,
- d denotes an integer from 0 to 50, and
- e is a number from 0 to 50, or
- (b) —(CH2—)fOR5,
- in which
- R5 denotes each and independently from another hydrogen, alkyl or carboxyl radical or a dimethyl propane radical containing ether groups if desired, and
- f denotes an integer from 2 to 20, or
- (c) —(CH2—)g(OC2H4—)h(OC3H8)j(OCH2CH(C6H5))kOR6
- in which
- R6 is a hydrogen, alkyl or carboxyl radical,
- g is a number from 2 to 6,
- h is a number from 0 to 20,
- i is a number from 1 to 50,
- j is a number from 0 to 10, and
- k is a number from 0 to 10, or
- (d) correspond to the radical R1,
- with the proviso that in the average molecule at least one radical R2 has the definition (a), a is a number from 1 to 500, and b is a number from 0 to 10.
Dependencies are inferred from the claim text.