Use of carbon dioxide to improve caustic washing of alkylene oxide / alkenyl benzene monomer streams
AssigneeLyondell Chemical Technology, L.P.
InventorsDavid W. Leyshon, Sandor Nagy, Elizabeth I. Ross-Medgaarden
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Abstract
A method for removing metal salts from alkylaromatic oxidate streams used for alkene oxide production, or used in the co-production of propylene oxide and styrene monomer (“POSM”), and methods for caustic washing of oxidate streams formed in these processes. The concentration of metal salts carried over from a caustic washing may be reduced by washing the organic phase resulting from the caustic wash with water in the presence of carbon dioxide (CO2). The CO2 may be provided in any form, such as gaseous CO2, dry ice, carbonated water, supercritical (liquid) CO2, or any other suitable form.
Claims20
A process for treating an alkylaromatic oxidate stream used for alkene oxide production, the process comprising:
- providing an alkylaromatic oxidate stream comprising (i) an alkylaromatic hydroperoxide, (ii) at least one undesired compound, and (iii) an organic solvent;
- contacting the alkylaromatic oxidate stream with an aqueous alkali solution to form a mixture, followed by separating the mixture into an aqueous phase and an organic phase;
- and
- subjecting the organic phase to one or more washing and separating cycles, each cycle comprising washing the organic phase with water to form a subsequent mixture followed by separating the subsequent mixture into a subsequent aqueous phase and a subsequent organic phase, wherein at least one of the washing and separating cycles comprises washing the organic phase or any subsequent organic phase with water in the presence of carbon dioxide.
A process for the co-production of an alkene oxide and styrene monomer, the process comprising:
- contacting molecular oxygen with ethylbenzene to form an oxidate stream comprising ethylbenzene hydroperoxide and at least one undesired compound;
- contacting the oxidate stream with an aqueous alkali solution to form a mixture, followed by separating the mixture into an aqueous phase and an organic phase comprising ethylbenzene hydroperoxide;
- subjecting the organic phase to one or more washing and separating cycles, each cycle comprising washing the organic phase with water to form a subsequent mixture followed by separating the subsequent mixture into a subsequent aqueous phase and a subsequent organic phase comprising ethylbenzene hydroperoxide;
- contacting the ethylbenzene hydroperoxide of the subsequent organic phase with an alkene in the presence of a catalyst to form a reaction mixture comprising an alkene oxide and 1-phenylethanol;
- and
- dehydrating the 1-phenylethanol of the reaction mixture to provide styrene;
- wherein at least one of the washing and separating cycles comprises washing the organic phase or any subsequent organic phase with water in the presence of carbon dioxide.
A process for removing sodium salts formed in the co-production of propylene oxide and styrene monomer, the process comprising:
- providing an ethylbenzene oxidate stream comprising (i) ethylbenzene hydroperoxide, (ii) at least one undesired compound, and (iii) an organic solvent;
- contacting the ethylbenzene oxidate stream with an aqueous sodium hydroxide solution to form a mixture, followed by separating the mixture into an aqueous phase and an organic phase;
- subjecting the organic phase to one or more washing and separating cycles, each cycle comprising washing the organic phase with water to form a subsequent mixture followed by separating the subsequent mixture into a subsequent aqueous phase and a subsequent organic phase, wherein at least one of the washing and separating cycles comprises washing the organic phase or any subsequent organic phase with water in the presence of carbon dioxide;
- and
- directing a portion of any subsequent organic phase to a reactor.
Dependencies are inferred from the claim text.